Chirality Constraints in Crystal−Crystal Transformations:  Isotactic Poly(1-butene) versus Syndiotactic Polypropylene

Chirality Constraints in Crystal−Crystal Transformations:  Isotactic Poly(1-butene) versus Syndiotactic Polypropylene

Solid-state crystal−crystal transformations in polymers are limited by conformational and steric constraints when helical hands are involved in the initial, final, or both stages of the transformation. The constraints are illustrated by (a) the phase II to phase I transformation in isotactic poly(1-...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Macromolecules 1998-12, Vol.31 (26), p.9253-9257
Hauptverfasser: Lotz, B, Mathieu, C, Thierry, A, Lovinger, A. J, De Rosa, C, Ruiz de Ballesteros, O, Auriemma, F
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Structure, morphology and analysis
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 9257
container_issue 26
container_start_page 9253
container_title Macromolecules
container_volume 31
creator Lotz, B
Mathieu, C
Thierry, A
Lovinger, A. J
De Rosa, C
Ruiz de Ballesteros, O
Auriemma, F
description Solid-state crystal−crystal transformations in polymers are limited by conformational and steric constraints when helical hands are involved in the initial, final, or both stages of the transformation. The constraints are illustrated by (a) the phase II to phase I transformation in isotactic poly(1-butene), which preserves the chirality of the helices, and (b) the generation of unusual, chiral crystal phases of syndiotactic polypropylene when starting from an extended-chain crystal phase, whereas the stable structure is fully antichiral. In the latter case, the isochirality of the resulting helical phase indicates that the transformation is a cooperative process.
doi_str_mv 10.1021/ma9810215
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_27457453</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>27457453</sourcerecordid><originalsourceid>FETCH-LOGICAL-a421t-ad269c43887e93d19285793e43f83296780e5628c675b72435cb88684d8b3b733</originalsourceid><addsrcrecordid>eNpt0M9LHDEUB_AgCl21h_4Hc7ClHkbzYzJJvMlQrWCr4BaKl5DJZjB2dmbNy4hz86jX_on-JWbZRXsoPMiDfN578EXoE8EHBFNyODdKLhu-gSaEU5xzyfgmmmBMi1xRJT6gbYBbjAnhBZugsbrxwbQ-jlnVdxCD8V2EzHdZFUaIpn15-rvusmkwHTR9mJvokz16eXzOzqCPxkZvs8u-Hb-SvB6i69x-du8CDJBdjd3M_0sWoV-MbSK7aKsxLbiP63cH_Tr5Nq2-5-cXp2fV8XluCkpibma0VLZgUgqn2IwoKrlQzBWskYyqUkjseEmlLQWvBS0Yt7WUpSxmsma1YGwHfVntTZfvBgdRzz1Y17amc_0AmoqCp1rC_RW0oQcIrtGL4OcmjJpgvcxUv4Wb7N56qQFr2iYlYz28D5RUEKkSy1fMQ3QPb98m_NGlYILr6eWV_q1-qh_XJ0yL5D-vvLGgb_shdCmZ_5x_BSVIlpw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>27457453</pqid></control><display><type>article</type><title>Chirality Constraints in Crystal−Crystal Transformations:  Isotactic Poly(1-butene) versus Syndiotactic Polypropylene</title><source>ACS Publications</source><creator>Lotz, B ; Mathieu, C ; Thierry, A ; Lovinger, A. J ; De Rosa, C ; Ruiz de Ballesteros, O ; Auriemma, F</creator><creatorcontrib>Lotz, B ; Mathieu, C ; Thierry, A ; Lovinger, A. J ; De Rosa, C ; Ruiz de Ballesteros, O ; Auriemma, F</creatorcontrib><description>Solid-state crystal−crystal transformations in polymers are limited by conformational and steric constraints when helical hands are involved in the initial, final, or both stages of the transformation. The constraints are illustrated by (a) the phase II to phase I transformation in isotactic poly(1-butene), which preserves the chirality of the helices, and (b) the generation of unusual, chiral crystal phases of syndiotactic polypropylene when starting from an extended-chain crystal phase, whereas the stable structure is fully antichiral. In the latter case, the isochirality of the resulting helical phase indicates that the transformation is a cooperative process.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/ma9810215</identifier><identifier>CODEN: MAMOBX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Structure, morphology and analysis</subject><ispartof>Macromolecules, 1998-12, Vol.31 (26), p.9253-9257</ispartof><rights>Copyright © 1998 American Chemical Society</rights><rights>1999 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a421t-ad269c43887e93d19285793e43f83296780e5628c675b72435cb88684d8b3b733</citedby><cites>FETCH-LOGICAL-a421t-ad269c43887e93d19285793e43f83296780e5628c675b72435cb88684d8b3b733</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ma9810215$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ma9810215$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=1627189$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lotz, B</creatorcontrib><creatorcontrib>Mathieu, C</creatorcontrib><creatorcontrib>Thierry, A</creatorcontrib><creatorcontrib>Lovinger, A. J</creatorcontrib><creatorcontrib>De Rosa, C</creatorcontrib><creatorcontrib>Ruiz de Ballesteros, O</creatorcontrib><creatorcontrib>Auriemma, F</creatorcontrib><title>Chirality Constraints in Crystal−Crystal Transformations:  Isotactic Poly(1-butene) versus Syndiotactic Polypropylene</title><title>Macromolecules</title><addtitle>Macromolecules</addtitle><description>Solid-state crystal−crystal transformations in polymers are limited by conformational and steric constraints when helical hands are involved in the initial, final, or both stages of the transformation. The constraints are illustrated by (a) the phase II to phase I transformation in isotactic poly(1-butene), which preserves the chirality of the helices, and (b) the generation of unusual, chiral crystal phases of syndiotactic polypropylene when starting from an extended-chain crystal phase, whereas the stable structure is fully antichiral. In the latter case, the isochirality of the resulting helical phase indicates that the transformation is a cooperative process.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Structure, morphology and analysis</subject><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNpt0M9LHDEUB_AgCl21h_4Hc7ClHkbzYzJJvMlQrWCr4BaKl5DJZjB2dmbNy4hz86jX_on-JWbZRXsoPMiDfN578EXoE8EHBFNyODdKLhu-gSaEU5xzyfgmmmBMi1xRJT6gbYBbjAnhBZugsbrxwbQ-jlnVdxCD8V2EzHdZFUaIpn15-rvusmkwHTR9mJvokz16eXzOzqCPxkZvs8u-Hb-SvB6i69x-du8CDJBdjd3M_0sWoV-MbSK7aKsxLbiP63cH_Tr5Nq2-5-cXp2fV8XluCkpibma0VLZgUgqn2IwoKrlQzBWskYyqUkjseEmlLQWvBS0Yt7WUpSxmsma1YGwHfVntTZfvBgdRzz1Y17amc_0AmoqCp1rC_RW0oQcIrtGL4OcmjJpgvcxUv4Wb7N56qQFr2iYlYz28D5RUEKkSy1fMQ3QPb98m_NGlYILr6eWV_q1-qh_XJ0yL5D-vvLGgb_shdCmZ_5x_BSVIlpw</recordid><startdate>19981229</startdate><enddate>19981229</enddate><creator>Lotz, B</creator><creator>Mathieu, C</creator><creator>Thierry, A</creator><creator>Lovinger, A. J</creator><creator>De Rosa, C</creator><creator>Ruiz de Ballesteros, O</creator><creator>Auriemma, F</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19981229</creationdate><title>Chirality Constraints in Crystal−Crystal Transformations:  Isotactic Poly(1-butene) versus Syndiotactic Polypropylene</title><author>Lotz, B ; Mathieu, C ; Thierry, A ; Lovinger, A. J ; De Rosa, C ; Ruiz de Ballesteros, O ; Auriemma, F</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a421t-ad269c43887e93d19285793e43f83296780e5628c675b72435cb88684d8b3b733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Structure, morphology and analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lotz, B</creatorcontrib><creatorcontrib>Mathieu, C</creatorcontrib><creatorcontrib>Thierry, A</creatorcontrib><creatorcontrib>Lovinger, A. J</creatorcontrib><creatorcontrib>De Rosa, C</creatorcontrib><creatorcontrib>Ruiz de Ballesteros, O</creatorcontrib><creatorcontrib>Auriemma, F</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lotz, B</au><au>Mathieu, C</au><au>Thierry, A</au><au>Lovinger, A. J</au><au>De Rosa, C</au><au>Ruiz de Ballesteros, O</au><au>Auriemma, F</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chirality Constraints in Crystal−Crystal Transformations:  Isotactic Poly(1-butene) versus Syndiotactic Polypropylene</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>1998-12-29</date><risdate>1998</risdate><volume>31</volume><issue>26</issue><spage>9253</spage><epage>9257</epage><pages>9253-9257</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><coden>MAMOBX</coden><abstract>Solid-state crystal−crystal transformations in polymers are limited by conformational and steric constraints when helical hands are involved in the initial, final, or both stages of the transformation. The constraints are illustrated by (a) the phase II to phase I transformation in isotactic poly(1-butene), which preserves the chirality of the helices, and (b) the generation of unusual, chiral crystal phases of syndiotactic polypropylene when starting from an extended-chain crystal phase, whereas the stable structure is fully antichiral. In the latter case, the isochirality of the resulting helical phase indicates that the transformation is a cooperative process.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ma9810215</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0024-9297
ispartof Macromolecules, 1998-12, Vol.31 (26), p.9253-9257
issn 0024-9297
1520-5835
language eng
recordid cdi_proquest_miscellaneous_27457453
source ACS Publications
subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Structure, morphology and analysis
title Chirality Constraints in Crystal−Crystal Transformations:  Isotactic Poly(1-butene) versus Syndiotactic Polypropylene
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-09T13%3A20%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Chirality%20Constraints%20in%20Crystal%E2%88%92Crystal%20Transformations:%E2%80%89%20Isotactic%20Poly(1-butene)%20versus%20Syndiotactic%20Polypropylene&rft.jtitle=Macromolecules&rft.au=Lotz,%20B&rft.date=1998-12-29&rft.volume=31&rft.issue=26&rft.spage=9253&rft.epage=9257&rft.pages=9253-9257&rft.issn=0024-9297&rft.eissn=1520-5835&rft.coden=MAMOBX&rft_id=info:doi/10.1021/ma9810215&rft_dat=%3Cproquest_cross%3E27457453%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=27457453&rft_id=info:pmid/&rfr_iscdi=true