Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors
Thin p-tert-butyl calix[4]arene and p-tert-butyl calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical microsensors based on an E.I.S. (Electrolyte-Insulator-Semiconductor) structure. Electrochemical capacity measurements were made to test a...
Gespeichert in:
| Veröffentlicht in: | Electrochimica acta 1998-01, Vol.43 (8), p.841-847 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 847 |
|---|---|
| container_issue | 8 |
| container_start_page | 841 |
| container_title | Electrochimica acta |
| container_volume | 43 |
| creator | Mlika, R. Ouada, H.Ben Chaabane, R.Ben Gamoudi, M. Guillaud, G. Jaffrezic-Renault, N. Lamartine, R. |
| description | Thin p-tert-butyl calix[4]arene and p-tert-butyl calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical microsensors based on an E.I.S. (Electrolyte-Insulator-Semiconductor) structure. Electrochemical capacity measurements were made to test and calibrate physico-chemical sensors with regards to their sensitivity and selectivity. The sensing properties of calix[4]arene and calix[6]arene towards alkaline and heavy metal ions were tested. Both devices have shown Nernstian response and a wide working pH range. The former responded well to sodium ions and the latter to nickel ions, thus partial selectivity for these ions is shown. The improved lifetime (compared with membranes prepared by physical adsorption techniques) and sensitivity observed for these films indicates that these structures are worthy of further developments. |
| doi_str_mv | 10.1016/S0013-4686(97)00259-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_27454408</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0013468697002594</els_id><sourcerecordid>27454408</sourcerecordid><originalsourceid>FETCH-LOGICAL-c367t-3c768f2c35e2f8fd3a645f929e4196b537e6617ae0146d9e01b443e012012a063</originalsourceid><addsrcrecordid>eNqFkE1LxDAQhoMouK7-BKEHET20Jk2atCeRZdWFBQ-r55CmU4z0Y820ov_edHfxKgReQp6ZyTyEXDKaMMrk3YZSxmMhc3lTqFtK06yIxRGZsVzxmOdZcUxmf8gpOUP8oJQqqeiMrBemcd_GQwdRC23pTQcY9V2E0Drbd9Voh95HOJY4eDOEtzpcl8kq2SSRfZ8g0wS4w97jOTmpTYNwccg5eXtcvi6e4_XL02rxsI4tl2qIuVUyr1PLM0jrvK64kSKri7QAwQpZZlyBlEwZoEzIqghRCsFDpOEYKvmcXO_7bn3_OQIOunVooWnC5_sRdapEJgTNA5jtQet7RA-13nrXGv-jGdWTO71zpycxulB6506LUHd1GGAw7FcHK9bhX3HKBGdyan-_xyAs--XAa7QOOguV82AHXfXun0G_ilWB3Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>27454408</pqid></control><display><type>article</type><title>Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors</title><source>Elsevier ScienceDirect Journals</source><creator>Mlika, R. ; Ouada, H.Ben ; Chaabane, R.Ben ; Gamoudi, M. ; Guillaud, G. ; Jaffrezic-Renault, N. ; Lamartine, R.</creator><creatorcontrib>Mlika, R. ; Ouada, H.Ben ; Chaabane, R.Ben ; Gamoudi, M. ; Guillaud, G. ; Jaffrezic-Renault, N. ; Lamartine, R.</creatorcontrib><description>Thin p-tert-butyl calix[4]arene and p-tert-butyl calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical microsensors based on an E.I.S. (Electrolyte-Insulator-Semiconductor) structure. Electrochemical capacity measurements were made to test and calibrate physico-chemical sensors with regards to their sensitivity and selectivity. The sensing properties of calix[4]arene and calix[6]arene towards alkaline and heavy metal ions were tested. Both devices have shown Nernstian response and a wide working pH range. The former responded well to sodium ions and the latter to nickel ions, thus partial selectivity for these ions is shown. The improved lifetime (compared with membranes prepared by physical adsorption techniques) and sensitivity observed for these films indicates that these structures are worthy of further developments.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/S0013-4686(97)00259-4</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>calixarene ; Chemistry ; electrochemical capacity ; Electrochemistry ; Electrodes: preparations and properties ; evaporation ; Exact sciences and technology ; General and physical chemistry ; Ion selective electrodes ; isemiconductor ; sensor</subject><ispartof>Electrochimica acta, 1998-01, Vol.43 (8), p.841-847</ispartof><rights>1996 Elsevier Science Ltd</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-3c768f2c35e2f8fd3a645f929e4196b537e6617ae0146d9e01b443e012012a063</citedby><cites>FETCH-LOGICAL-c367t-3c768f2c35e2f8fd3a645f929e4196b537e6617ae0146d9e01b443e012012a063</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0013468697002594$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2143168$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Mlika, R.</creatorcontrib><creatorcontrib>Ouada, H.Ben</creatorcontrib><creatorcontrib>Chaabane, R.Ben</creatorcontrib><creatorcontrib>Gamoudi, M.</creatorcontrib><creatorcontrib>Guillaud, G.</creatorcontrib><creatorcontrib>Jaffrezic-Renault, N.</creatorcontrib><creatorcontrib>Lamartine, R.</creatorcontrib><title>Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors</title><title>Electrochimica acta</title><description>Thin p-tert-butyl calix[4]arene and p-tert-butyl calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical microsensors based on an E.I.S. (Electrolyte-Insulator-Semiconductor) structure. Electrochemical capacity measurements were made to test and calibrate physico-chemical sensors with regards to their sensitivity and selectivity. The sensing properties of calix[4]arene and calix[6]arene towards alkaline and heavy metal ions were tested. Both devices have shown Nernstian response and a wide working pH range. The former responded well to sodium ions and the latter to nickel ions, thus partial selectivity for these ions is shown. The improved lifetime (compared with membranes prepared by physical adsorption techniques) and sensitivity observed for these films indicates that these structures are worthy of further developments.</description><subject>calixarene</subject><subject>Chemistry</subject><subject>electrochemical capacity</subject><subject>Electrochemistry</subject><subject>Electrodes: preparations and properties</subject><subject>evaporation</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Ion selective electrodes</subject><subject>isemiconductor</subject><subject>sensor</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAQhoMouK7-BKEHET20Jk2atCeRZdWFBQ-r55CmU4z0Y820ov_edHfxKgReQp6ZyTyEXDKaMMrk3YZSxmMhc3lTqFtK06yIxRGZsVzxmOdZcUxmf8gpOUP8oJQqqeiMrBemcd_GQwdRC23pTQcY9V2E0Drbd9Voh95HOJY4eDOEtzpcl8kq2SSRfZ8g0wS4w97jOTmpTYNwccg5eXtcvi6e4_XL02rxsI4tl2qIuVUyr1PLM0jrvK64kSKri7QAwQpZZlyBlEwZoEzIqghRCsFDpOEYKvmcXO_7bn3_OQIOunVooWnC5_sRdapEJgTNA5jtQet7RA-13nrXGv-jGdWTO71zpycxulB6506LUHd1GGAw7FcHK9bhX3HKBGdyan-_xyAs--XAa7QOOguV82AHXfXun0G_ilWB3Q</recordid><startdate>19980101</startdate><enddate>19980101</enddate><creator>Mlika, R.</creator><creator>Ouada, H.Ben</creator><creator>Chaabane, R.Ben</creator><creator>Gamoudi, M.</creator><creator>Guillaud, G.</creator><creator>Jaffrezic-Renault, N.</creator><creator>Lamartine, R.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>19980101</creationdate><title>Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors</title><author>Mlika, R. ; Ouada, H.Ben ; Chaabane, R.Ben ; Gamoudi, M. ; Guillaud, G. ; Jaffrezic-Renault, N. ; Lamartine, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-3c768f2c35e2f8fd3a645f929e4196b537e6617ae0146d9e01b443e012012a063</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>calixarene</topic><topic>Chemistry</topic><topic>electrochemical capacity</topic><topic>Electrochemistry</topic><topic>Electrodes: preparations and properties</topic><topic>evaporation</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Ion selective electrodes</topic><topic>isemiconductor</topic><topic>sensor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mlika, R.</creatorcontrib><creatorcontrib>Ouada, H.Ben</creatorcontrib><creatorcontrib>Chaabane, R.Ben</creatorcontrib><creatorcontrib>Gamoudi, M.</creatorcontrib><creatorcontrib>Guillaud, G.</creatorcontrib><creatorcontrib>Jaffrezic-Renault, N.</creatorcontrib><creatorcontrib>Lamartine, R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mlika, R.</au><au>Ouada, H.Ben</au><au>Chaabane, R.Ben</au><au>Gamoudi, M.</au><au>Guillaud, G.</au><au>Jaffrezic-Renault, N.</au><au>Lamartine, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors</atitle><jtitle>Electrochimica acta</jtitle><date>1998-01-01</date><risdate>1998</risdate><volume>43</volume><issue>8</issue><spage>841</spage><epage>847</epage><pages>841-847</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>Thin p-tert-butyl calix[4]arene and p-tert-butyl calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical microsensors based on an E.I.S. (Electrolyte-Insulator-Semiconductor) structure. Electrochemical capacity measurements were made to test and calibrate physico-chemical sensors with regards to their sensitivity and selectivity. The sensing properties of calix[4]arene and calix[6]arene towards alkaline and heavy metal ions were tested. Both devices have shown Nernstian response and a wide working pH range. The former responded well to sodium ions and the latter to nickel ions, thus partial selectivity for these ions is shown. The improved lifetime (compared with membranes prepared by physical adsorption techniques) and sensitivity observed for these films indicates that these structures are worthy of further developments.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0013-4686(97)00259-4</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 1998-01, Vol.43 (8), p.841-847 |
| issn | 0013-4686 1873-3859 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_27454408 |
| source | Elsevier ScienceDirect Journals |
| subjects | calixarene Chemistry electrochemical capacity Electrochemistry Electrodes: preparations and properties evaporation Exact sciences and technology General and physical chemistry Ion selective electrodes isemiconductor sensor |
| title | Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T23%3A55%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Calixarene%20membranes%20on%20semiconductor%20substrates%20for%20E.I.S.%20chemical%20sensors&rft.jtitle=Electrochimica%20acta&rft.au=Mlika,%20R.&rft.date=1998-01-01&rft.volume=43&rft.issue=8&rft.spage=841&rft.epage=847&rft.pages=841-847&rft.issn=0013-4686&rft.eissn=1873-3859&rft.coden=ELCAAV&rft_id=info:doi/10.1016/S0013-4686(97)00259-4&rft_dat=%3Cproquest_cross%3E27454408%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=27454408&rft_id=info:pmid/&rft_els_id=S0013468697002594&rfr_iscdi=true |