New metal-free one-pot synthesis of α-2-deoxy-Ulosides by microwave-assisted double Michael Addition of β-enamino ketones

New metal-free one-pot synthesis of α-2-deoxy-ulosides in moderate to good yields by microwave-assisted double Michael addition of various O-nucleophiles to β-enamino ketones in the presence of 12 N HCl. These glycosyl additions occurred with high α-stereoselectivity and were complete in 10–25 min i...

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Veröffentlicht in:	Carbohydrate research 2023-01, Vol.523, p.108712-108712, Article 108712
Hauptverfasser:	Lin, Pin-Chun, Lin, Zi-Ping, Chen, Po-Yen, Hsieh, Min-Tsang, Lin, Hui-Chang
Format:	Artikel
Sprache:	eng
Schlagworte:	2-Deoxy-Uloside 2-Deoxyglycoside carbohydrates chemical reactions Ketones Metals Michael addition Microwave microwave treatment Microwaves synthesis β-Enamino ketone
Online-Zugang:	Volltext
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