The evolution of oxidation stresses in zirconia thermal barrier coated superalloy leading to spalling failure

The evolution of the stresses in the aluminum oxide formed beneath a zirconia thermal barrier coating during high-temperature oxidation has been measured from the piezospectroscopic shift in the R-line photoluminescence from Cr 3+ impurities incorporated into the growing aluminum oxide scale. The ea...

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Veröffentlicht in:Surface & coatings technology 1997-10, Vol.94 (1-3), p.89-93
Hauptverfasser: Clarke, D.R., Christensen, R.J., Tolpygo, V.
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creator Clarke, D.R.
Christensen, R.J.
Tolpygo, V.
description The evolution of the stresses in the aluminum oxide formed beneath a zirconia thermal barrier coating during high-temperature oxidation has been measured from the piezospectroscopic shift in the R-line photoluminescence from Cr 3+ impurities incorporated into the growing aluminum oxide scale. The early stages of oxidation are associated with concurrent phase transformations in the aluminum oxide leading to the stable alpha-alumina phase. On the basis of microstructural observations and the broadening of the luminescence lines, it is suggested that spalling failure occurs as a result of linking together of localized decohesion of the oxide/bond-coat interface, a process accelerated by moisture enhanced sub-critical crack growth at the interface.
doi_str_mv 10.1016/S0257-8972(97)00483-0
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source Elsevier ScienceDirect Journals
subjects Applied sciences
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Luminescence
Mechanical and acoustical properties
Metals. Metallurgy
Oxidation
Physical properties of thin films, nonelectronic
Physics
Stresses
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
TBC
title The evolution of oxidation stresses in zirconia thermal barrier coated superalloy leading to spalling failure
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