Thermodynamics of the interactions between liquid breeders and ceramic coating materials

Thermodynamics of the interactions between liquid breeders and ceramic coating materials

The thermodynamic stabilities (Δ ri G) of various ceramics towards Pb Li alloys have been evaluated as a function of temperature, lithium composition and, for lithium, non-metal solute concentration. For non-metal saturated alloys, both increasing temperature and decreasing lithium composition (from...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of nuclear materials 1997-09, Vol.248 (1-3), p.140-146
Hauptverfasser: Hubberstey, Peter, Sample, Tony
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 146
container_issue 1-3
container_start_page 140
container_title Journal of nuclear materials
container_volume 248
creator Hubberstey, Peter
Sample, Tony
description The thermodynamic stabilities (Δ ri G) of various ceramics towards Pb Li alloys have been evaluated as a function of temperature, lithium composition and, for lithium, non-metal solute concentration. For non-metal saturated alloys, both increasing temperature and decreasing lithium composition (from lithium to Pb -17Li) lead to increased stability (more positive Δ r G values). Reducing non-metal solute concentration in lithium by cold trapping leads to decreased stability. Of the ceramics presently being assessed as coating materials, AlN, TiN, TiC, Y 2O 3 and CaO are stable in reactor grade Pb 17Li and reactor grade lithium, β-SiC, Al 2O 3, SiO 2 and MgO are stable in Pb 17Li but not lithium and Cr 2O 3 is unstable in both breeders.
doi_str_mv 10.1016/S0022-3115(97)00204-3
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_27399847</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0022311597002043</els_id><sourcerecordid>27399847</sourcerecordid><originalsourceid>FETCH-LOGICAL-c404t-2fa24edc37fd7e5a493e74fdb742fb9fffc143b64848abe18d89b50a25dc61ef3</originalsourceid><addsrcrecordid>eNqFkEtLAzEUhYMoWKs_QchKdDGa1zSTlUjxBQUXVnAXMsmNjcyjTVKl_95pK25dHS5834F7EDqn5JoSOrl5JYSxglNaXip5NRxEFPwAjWgleSEqRg7R6A85RicpfRJCSkXKEXqfLyC2vdt0pg024d7jvAAcugzR2Bz6LuEa8jdAh5uwWgeH6wjgICZsOoftgA0itr3JofvArRnEYJp0io78EHD2m2P09nA_nz4Vs5fH5-ndrLCCiFwwb5gAZ7n0TkJphOIghXe1FMzXyntvqeD1RFSiMjXQylWqLolhpbMTCp6P0cW-dxn71RpS1m1IFprGdNCvk2aSK1UJOYDlHrSxTymC18sYWhM3mhK93VHvdtTbkbSSerej5oN3u_dg-OIrQNTJBugsuBDBZu368E_DD4C4fHg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>27399847</pqid></control><display><type>article</type><title>Thermodynamics of the interactions between liquid breeders and ceramic coating materials</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Hubberstey, Peter ; Sample, Tony</creator><creatorcontrib>Hubberstey, Peter ; Sample, Tony</creatorcontrib><description>The thermodynamic stabilities (Δ ri G) of various ceramics towards Pb Li alloys have been evaluated as a function of temperature, lithium composition and, for lithium, non-metal solute concentration. For non-metal saturated alloys, both increasing temperature and decreasing lithium composition (from lithium to Pb -17Li) lead to increased stability (more positive Δ r G values). Reducing non-metal solute concentration in lithium by cold trapping leads to decreased stability. Of the ceramics presently being assessed as coating materials, AlN, TiN, TiC, Y 2O 3 and CaO are stable in reactor grade Pb 17Li and reactor grade lithium, β-SiC, Al 2O 3, SiO 2 and MgO are stable in Pb 17Li but not lithium and Cr 2O 3 is unstable in both breeders.</description><identifier>ISSN: 0022-3115</identifier><identifier>EISSN: 1873-4820</identifier><identifier>DOI: 10.1016/S0022-3115(97)00204-3</identifier><language>eng</language><publisher>Elsevier B.V</publisher><ispartof>Journal of nuclear materials, 1997-09, Vol.248 (1-3), p.140-146</ispartof><rights>1997 Elsevier Science B.V. All rights reserved</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c404t-2fa24edc37fd7e5a493e74fdb742fb9fffc143b64848abe18d89b50a25dc61ef3</citedby><cites>FETCH-LOGICAL-c404t-2fa24edc37fd7e5a493e74fdb742fb9fffc143b64848abe18d89b50a25dc61ef3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0022-3115(97)00204-3$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,45974</link.rule.ids></links><search><creatorcontrib>Hubberstey, Peter</creatorcontrib><creatorcontrib>Sample, Tony</creatorcontrib><title>Thermodynamics of the interactions between liquid breeders and ceramic coating materials</title><title>Journal of nuclear materials</title><description>The thermodynamic stabilities (Δ ri G) of various ceramics towards Pb Li alloys have been evaluated as a function of temperature, lithium composition and, for lithium, non-metal solute concentration. For non-metal saturated alloys, both increasing temperature and decreasing lithium composition (from lithium to Pb -17Li) lead to increased stability (more positive Δ r G values). Reducing non-metal solute concentration in lithium by cold trapping leads to decreased stability. Of the ceramics presently being assessed as coating materials, AlN, TiN, TiC, Y 2O 3 and CaO are stable in reactor grade Pb 17Li and reactor grade lithium, β-SiC, Al 2O 3, SiO 2 and MgO are stable in Pb 17Li but not lithium and Cr 2O 3 is unstable in both breeders.</description><issn>0022-3115</issn><issn>1873-4820</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEUhYMoWKs_QchKdDGa1zSTlUjxBQUXVnAXMsmNjcyjTVKl_95pK25dHS5834F7EDqn5JoSOrl5JYSxglNaXip5NRxEFPwAjWgleSEqRg7R6A85RicpfRJCSkXKEXqfLyC2vdt0pg024d7jvAAcugzR2Bz6LuEa8jdAh5uwWgeH6wjgICZsOoftgA0itr3JofvArRnEYJp0io78EHD2m2P09nA_nz4Vs5fH5-ndrLCCiFwwb5gAZ7n0TkJphOIghXe1FMzXyntvqeD1RFSiMjXQylWqLolhpbMTCp6P0cW-dxn71RpS1m1IFprGdNCvk2aSK1UJOYDlHrSxTymC18sYWhM3mhK93VHvdtTbkbSSerej5oN3u_dg-OIrQNTJBugsuBDBZu368E_DD4C4fHg</recordid><startdate>19970901</startdate><enddate>19970901</enddate><creator>Hubberstey, Peter</creator><creator>Sample, Tony</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19970901</creationdate><title>Thermodynamics of the interactions between liquid breeders and ceramic coating materials</title><author>Hubberstey, Peter ; Sample, Tony</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c404t-2fa24edc37fd7e5a493e74fdb742fb9fffc143b64848abe18d89b50a25dc61ef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hubberstey, Peter</creatorcontrib><creatorcontrib>Sample, Tony</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of nuclear materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hubberstey, Peter</au><au>Sample, Tony</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamics of the interactions between liquid breeders and ceramic coating materials</atitle><jtitle>Journal of nuclear materials</jtitle><date>1997-09-01</date><risdate>1997</risdate><volume>248</volume><issue>1-3</issue><spage>140</spage><epage>146</epage><pages>140-146</pages><issn>0022-3115</issn><eissn>1873-4820</eissn><abstract>The thermodynamic stabilities (Δ ri G) of various ceramics towards Pb Li alloys have been evaluated as a function of temperature, lithium composition and, for lithium, non-metal solute concentration. For non-metal saturated alloys, both increasing temperature and decreasing lithium composition (from lithium to Pb -17Li) lead to increased stability (more positive Δ r G values). Reducing non-metal solute concentration in lithium by cold trapping leads to decreased stability. Of the ceramics presently being assessed as coating materials, AlN, TiN, TiC, Y 2O 3 and CaO are stable in reactor grade Pb 17Li and reactor grade lithium, β-SiC, Al 2O 3, SiO 2 and MgO are stable in Pb 17Li but not lithium and Cr 2O 3 is unstable in both breeders.</abstract><pub>Elsevier B.V</pub><doi>10.1016/S0022-3115(97)00204-3</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0022-3115
ispartof Journal of nuclear materials, 1997-09, Vol.248 (1-3), p.140-146
issn 0022-3115
1873-4820
language eng
recordid cdi_proquest_miscellaneous_27399847
source Elsevier ScienceDirect Journals Complete
title Thermodynamics of the interactions between liquid breeders and ceramic coating materials
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-22T17%3A02%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermodynamics%20of%20the%20interactions%20between%20liquid%20breeders%20and%20ceramic%20coating%20materials&rft.jtitle=Journal%20of%20nuclear%20materials&rft.au=Hubberstey,%20Peter&rft.date=1997-09-01&rft.volume=248&rft.issue=1-3&rft.spage=140&rft.epage=146&rft.pages=140-146&rft.issn=0022-3115&rft.eissn=1873-4820&rft_id=info:doi/10.1016/S0022-3115(97)00204-3&rft_dat=%3Cproquest_cross%3E27399847%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=27399847&rft_id=info:pmid/&rft_els_id=S0022311597002043&rfr_iscdi=true