Sorption behavior of rutherfordium and thorium from HCl/Hf containing aqueous solution
The sorption was studied of element 104 (rutherfordium, Rf) and thorium on the strongly acidic cation exchanger DOWEX 50mult 8. The experiments were carried out on-line. Rf is strongly retained on cation exchange resins from diluted HCl/HF solutions in a concentration range of 0.05 to 0.1 M HCl and...
Gespeichert in:
| Veröffentlicht in: | Journal of alloys and compounds 1997-09, Vol.271-273, p.307-311 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 311 |
|---|---|
| container_issue | |
| container_start_page | 307 |
| container_title | Journal of alloys and compounds |
| container_volume | 271-273 |
| creator | Schumann, D Nitsche, H Taut, S T Jost, D T Gaggeler, H W Yakushev, A B Buklanov, G V Domanov, V P Lien, D T Kubica, B Misiak, R Szeglowski, E |
| description | The sorption was studied of element 104 (rutherfordium, Rf) and thorium on the strongly acidic cation exchanger DOWEX 50mult 8. The experiments were carried out on-line. Rf is strongly retained on cation exchange resins from diluted HCl/HF solutions in a concentration range of 0.05 to 0.1 M HCl and HF concentrations up to 0.01 M. This behavior is similar to its pseudohomologue thorium and very different from its lighter homologue hafnium which is desorbed from DOWEX 50mult 8 at HF concentrations above 10 exp -3 M. The tested ion exchange system is suitable for fast on-line separation of element 106 (seaborgium, Sb) from all other contaminations and its decay product Rf. Therefore, it allows the indirect identification of Sg. |
| format | Article |
| fullrecord | <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_27358601</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>27358601</sourcerecordid><originalsourceid>FETCH-proquest_miscellaneous_273586013</originalsourceid><addsrcrecordid>eNqNjL0OgjAURjtoIv68w53ciIUGhZlo2DWupkIrNaUXb1ufX0l8AKfzDec7M5bwKi_SUpTlgi29f3LOs0pkCbuekcZg0MFd9fJtkAA1UAy9Io3UmTiAdB2EHmnamnCApra7RkOLLkjjjHuAfEWF0YNHG6fams21tF5tflyx7el4qZt0JPyqPtwG41tlrXTT75YfRFHueSb-Fj-_8ESe</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>27358601</pqid></control><display><type>article</type><title>Sorption behavior of rutherfordium and thorium from HCl/Hf containing aqueous solution</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Schumann, D ; Nitsche, H ; Taut, S T ; Jost, D T ; Gaggeler, H W ; Yakushev, A B ; Buklanov, G V ; Domanov, V P ; Lien, D T ; Kubica, B ; Misiak, R ; Szeglowski, E</creator><creatorcontrib>Schumann, D ; Nitsche, H ; Taut, S T ; Jost, D T ; Gaggeler, H W ; Yakushev, A B ; Buklanov, G V ; Domanov, V P ; Lien, D T ; Kubica, B ; Misiak, R ; Szeglowski, E</creatorcontrib><description>The sorption was studied of element 104 (rutherfordium, Rf) and thorium on the strongly acidic cation exchanger DOWEX 50mult 8. The experiments were carried out on-line. Rf is strongly retained on cation exchange resins from diluted HCl/HF solutions in a concentration range of 0.05 to 0.1 M HCl and HF concentrations up to 0.01 M. This behavior is similar to its pseudohomologue thorium and very different from its lighter homologue hafnium which is desorbed from DOWEX 50mult 8 at HF concentrations above 10 exp -3 M. The tested ion exchange system is suitable for fast on-line separation of element 106 (seaborgium, Sb) from all other contaminations and its decay product Rf. Therefore, it allows the indirect identification of Sg.</description><identifier>ISSN: 0925-8388</identifier><language>eng</language><ispartof>Journal of alloys and compounds, 1997-09, Vol.271-273, p.307-311</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784</link.rule.ids></links><search><creatorcontrib>Schumann, D</creatorcontrib><creatorcontrib>Nitsche, H</creatorcontrib><creatorcontrib>Taut, S T</creatorcontrib><creatorcontrib>Jost, D T</creatorcontrib><creatorcontrib>Gaggeler, H W</creatorcontrib><creatorcontrib>Yakushev, A B</creatorcontrib><creatorcontrib>Buklanov, G V</creatorcontrib><creatorcontrib>Domanov, V P</creatorcontrib><creatorcontrib>Lien, D T</creatorcontrib><creatorcontrib>Kubica, B</creatorcontrib><creatorcontrib>Misiak, R</creatorcontrib><creatorcontrib>Szeglowski, E</creatorcontrib><title>Sorption behavior of rutherfordium and thorium from HCl/Hf containing aqueous solution</title><title>Journal of alloys and compounds</title><description>The sorption was studied of element 104 (rutherfordium, Rf) and thorium on the strongly acidic cation exchanger DOWEX 50mult 8. The experiments were carried out on-line. Rf is strongly retained on cation exchange resins from diluted HCl/HF solutions in a concentration range of 0.05 to 0.1 M HCl and HF concentrations up to 0.01 M. This behavior is similar to its pseudohomologue thorium and very different from its lighter homologue hafnium which is desorbed from DOWEX 50mult 8 at HF concentrations above 10 exp -3 M. The tested ion exchange system is suitable for fast on-line separation of element 106 (seaborgium, Sb) from all other contaminations and its decay product Rf. Therefore, it allows the indirect identification of Sg.</description><issn>0925-8388</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqNjL0OgjAURjtoIv68w53ciIUGhZlo2DWupkIrNaUXb1ufX0l8AKfzDec7M5bwKi_SUpTlgi29f3LOs0pkCbuekcZg0MFd9fJtkAA1UAy9Io3UmTiAdB2EHmnamnCApra7RkOLLkjjjHuAfEWF0YNHG6fams21tF5tflyx7el4qZt0JPyqPtwG41tlrXTT75YfRFHueSb-Fj-_8ESe</recordid><startdate>19970921</startdate><enddate>19970921</enddate><creator>Schumann, D</creator><creator>Nitsche, H</creator><creator>Taut, S T</creator><creator>Jost, D T</creator><creator>Gaggeler, H W</creator><creator>Yakushev, A B</creator><creator>Buklanov, G V</creator><creator>Domanov, V P</creator><creator>Lien, D T</creator><creator>Kubica, B</creator><creator>Misiak, R</creator><creator>Szeglowski, E</creator><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19970921</creationdate><title>Sorption behavior of rutherfordium and thorium from HCl/Hf containing aqueous solution</title><author>Schumann, D ; Nitsche, H ; Taut, S T ; Jost, D T ; Gaggeler, H W ; Yakushev, A B ; Buklanov, G V ; Domanov, V P ; Lien, D T ; Kubica, B ; Misiak, R ; Szeglowski, E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_273586013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schumann, D</creatorcontrib><creatorcontrib>Nitsche, H</creatorcontrib><creatorcontrib>Taut, S T</creatorcontrib><creatorcontrib>Jost, D T</creatorcontrib><creatorcontrib>Gaggeler, H W</creatorcontrib><creatorcontrib>Yakushev, A B</creatorcontrib><creatorcontrib>Buklanov, G V</creatorcontrib><creatorcontrib>Domanov, V P</creatorcontrib><creatorcontrib>Lien, D T</creatorcontrib><creatorcontrib>Kubica, B</creatorcontrib><creatorcontrib>Misiak, R</creatorcontrib><creatorcontrib>Szeglowski, E</creatorcontrib><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schumann, D</au><au>Nitsche, H</au><au>Taut, S T</au><au>Jost, D T</au><au>Gaggeler, H W</au><au>Yakushev, A B</au><au>Buklanov, G V</au><au>Domanov, V P</au><au>Lien, D T</au><au>Kubica, B</au><au>Misiak, R</au><au>Szeglowski, E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sorption behavior of rutherfordium and thorium from HCl/Hf containing aqueous solution</atitle><jtitle>Journal of alloys and compounds</jtitle><date>1997-09-21</date><risdate>1997</risdate><volume>271-273</volume><spage>307</spage><epage>311</epage><pages>307-311</pages><issn>0925-8388</issn><abstract>The sorption was studied of element 104 (rutherfordium, Rf) and thorium on the strongly acidic cation exchanger DOWEX 50mult 8. The experiments were carried out on-line. Rf is strongly retained on cation exchange resins from diluted HCl/HF solutions in a concentration range of 0.05 to 0.1 M HCl and HF concentrations up to 0.01 M. This behavior is similar to its pseudohomologue thorium and very different from its lighter homologue hafnium which is desorbed from DOWEX 50mult 8 at HF concentrations above 10 exp -3 M. The tested ion exchange system is suitable for fast on-line separation of element 106 (seaborgium, Sb) from all other contaminations and its decay product Rf. Therefore, it allows the indirect identification of Sg.</abstract></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0925-8388 |
| ispartof | Journal of alloys and compounds, 1997-09, Vol.271-273, p.307-311 |
| issn | 0925-8388 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_27358601 |
| source | Elsevier ScienceDirect Journals Complete |
| title | Sorption behavior of rutherfordium and thorium from HCl/Hf containing aqueous solution |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T12%3A45%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Sorption%20behavior%20of%20rutherfordium%20and%20thorium%20from%20HCl/Hf%20containing%20aqueous%20solution&rft.jtitle=Journal%20of%20alloys%20and%20compounds&rft.au=Schumann,%20D&rft.date=1997-09-21&rft.volume=271-273&rft.spage=307&rft.epage=311&rft.pages=307-311&rft.issn=0925-8388&rft_id=info:doi/&rft_dat=%3Cproquest%3E27358601%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=27358601&rft_id=info:pmid/&rfr_iscdi=true |