Crystallization of Celsian (BaAl2Si2O8) Glass

The fabrication and crystallization of stoichiometric and near‐stoichiometric celsian, BaAl2Si2O8 (BAS), glass made via melt and sol‐gel routes is reviewed. After considering celsian polymorphism and methods of stabilizing monoclinic celsian, some new experimental results are presented which show th...

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Veröffentlicht in:Journal of the American Ceramic Society 1995-08, Vol.78 (8), p.2180-2186
Hauptverfasser: Lee, William E., Chen, Makan, James, Peter F.
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creator Lee, William E.
Chen, Makan
James, Peter F.
description The fabrication and crystallization of stoichiometric and near‐stoichiometric celsian, BaAl2Si2O8 (BAS), glass made via melt and sol‐gel routes is reviewed. After considering celsian polymorphism and methods of stabilizing monoclinic celsian, some new experimental results are presented which show that melt glass crystallizes predominantly via surface nucleation, but sol‐gel glass via volume nucleation. Possible reasons for this behavior and the kinetics of the crystallization process are examined.
doi_str_mv 10.1111/j.1151-2916.1995.tb08633.x
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subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of crystal growth
physics of crystal growth
Physics
Theory and models of crystal growth
physics of crystal growth, crystal morphology and orientation
Theory and models of film growth
title Crystallization of Celsian (BaAl2Si2O8) Glass
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