Active centre association in anionic polymerization. Its relation to the mechanism of polymerization of dienes in non-polar solvents

Active centre association in anionic polymerization. Its relation to the mechanism of polymerization of dienes in non-polar solvents

The dissociation mechanism suggested for lithium‐based polymerization in many cases requires a relationships between the degree of association of the active centres and the kinetic data. This connection has recently been questioned (R. N. Young, L. J. Fetters, J. S. Huang & R. Krishnamoorti, Pol...

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Veröffentlicht in:Polymer international 1995-12, Vol.38 (4), p.325-333
1. Verfasser: Bywater, S.
Format: Artikel
Sprache:eng
Schlagworte:
active centre association
anionic polymerization
Applied sciences
dienes
Exact sciences and technology
non-polar solvents
Organic polymers
organolithium compounds
Physicochemistry of polymers
Polymerization
polymerization mechanisms
Preparation, kinetics, thermodynamics, mechanism and catalysts
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container_title Polymer international
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description The dissociation mechanism suggested for lithium‐based polymerization in many cases requires a relationships between the degree of association of the active centres and the kinetic data. This connection has recently been questioned (R. N. Young, L. J. Fetters, J. S. Huang & R. Krishnamoorti, Polymer International, 33 (1994) 217). It is the purpose of the present communication to show that this questioning is not soundly based.
doi_str_mv 10.1002/pi.1995.210380403
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subjects active centre association
anionic polymerization
Applied sciences
dienes
Exact sciences and technology
non-polar solvents
Organic polymers
organolithium compounds
Physicochemistry of polymers
Polymerization
polymerization mechanisms
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Active centre association in anionic polymerization. Its relation to the mechanism of polymerization of dienes in non-polar solvents
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