Tetra-ammonium bis-(metforminium) di-μ6-oxido-tetra-μ3-oxido-tetra-deca-μ2-oxido-octa-oxidodeca-vanadium(V) hexa-hydrate

Tetra-ammonium bis-(metforminium) di-μ6-oxido-tetra-μ3-oxido-tetra-deca-μ2-oxido-octa-oxidodeca-vanadium(V) hexa-hydrate

The title compound, (NH4)4(C4H12N5)2[V10O28]·6H2O, crystallizes with the deca-vanadate anion placed on an inversion centre in space group P . This anion is surrounded by a first shell of ammonium cations and water mol-ecules, forming efficient N-H⋯O and O-H⋯O hydrogen bonds. A second shell includes...

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Veröffentlicht in:IUCrData 2021-06, Vol.6 (Pt 6), p.x210634
Hauptverfasser: Polito-Lucas, J Alberto, Núñez-Ávila, José A, Bernès, Sylvain, Pérez-Benítez, Aarón
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container_issue Pt 6
container_start_page x210634
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creator Polito-Lucas, J Alberto
Núñez-Ávila, José A
Bernès, Sylvain
Pérez-Benítez, Aarón
description The title compound, (NH4)4(C4H12N5)2[V10O28]·6H2O, crystallizes with the deca-vanadate anion placed on an inversion centre in space group P . This anion is surrounded by a first shell of ammonium cations and water mol-ecules, forming efficient N-H⋯O and O-H⋯O hydrogen bonds. A second shell includes metforminium monocations with a twisted geometry, also forming numerous inter-molecular hydrogen bonds. The complex three-dimensional network of non-covalent inter-actions affords a crystal structure in which the cations and anions are densely packed.The title compound, (NH4)4(C4H12N5)2[V10O28]·6H2O, crystallizes with the deca-vanadate anion placed on an inversion centre in space group P . This anion is surrounded by a first shell of ammonium cations and water mol-ecules, forming efficient N-H⋯O and O-H⋯O hydrogen bonds. A second shell includes metforminium monocations with a twisted geometry, also forming numerous inter-molecular hydrogen bonds. The complex three-dimensional network of non-covalent inter-actions affords a crystal structure in which the cations and anions are densely packed.
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title Tetra-ammonium bis-(metforminium) di-μ6-oxido-tetra-μ3-oxido-tetra-deca-μ2-oxido-octa-oxidodeca-vanadium(V) hexa-hydrate
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