Oxidation and Reduction Pathways in the Knowles Hydroamination via a Photoredox‐Catalyzed Radical Reaction

Systematic reaction path exploration revealed the entire mechanism of Knowles's light‐promoted catalytic intramolecular hydroamination. Bond formation/cleavage competes with single electron transfer (SET) between the catalyst and substrate. These processes are described by adiabatic processes t...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-01, Vol.62 (1), p.e202211936-n/a
Hauptverfasser:	Harabuchi, Yu, Hayashi, Hiroki, Takano, Hideaki, Mita, Tsuyoshi, Maeda, Satoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Adiabatic Adiabatic flow Adiabatic processes Catalysts Computational Chemistry Computer applications Electrode potentials Electron states Electron transfer Energy charge Hydroamination Photoredox Catalysis Potential energy Radical Reactions Reaction Networks Redox potential Reduction Single electrons Substrates
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