Changes in the properties of HDPE fibers upon radiation grafting with acrylic acid

The morphology and the physical and mechanical properties of graft‐modified polyethylene fibers have been studied. Two types of fibers, with the diameters of 10 μm (1.1 dtex) and 40 μm (7.5 dtex), were modified by radiation‐induced grafting with acrylic acid. The extent of grafting was determined gravimetrically. Confirmation of gravimetrically obtained values was achieved using conductometric titration. The fibers were hydrated at pH 2 and pH 7. The degree of swelling was 120% at pH 2 and 200% at pH 7. The transversal distribution of polyacrylic acid in the fibers was determined. Fibers were stained and observed with an optical microscope. The diffusion of the monomer into the bulk was found to be rather fast. The changes in the total crystalline content and the lamellar thickness distributions in consequence of irradiation and grafting were determined by differential scanning calorimetry analysis. The measurements showed no effects of irradiation on the crystallinity in either type of fiber, whereas a decreasing crystallinity caused by grafting was noticed in the 40 μm fibers. The lamellar thickness distributions narrowed upon irradiation, indicating recrystallization as a result of chain scission. Wide angle x‐ray scattering and Raman analysis of dry and hydrated fibers were conducted to study the behavior of the fibers in an aqueous environment. These results both showed a decreasing crystalline content caused by fiber hydration. Tensile tests were carried out to evaluate how grafting, hydration and Ca2+‐crosslinking of grafts affected the fiber strength. Grafting and Ca2+‐crosslinking, as well as hydration, resulted in a decreasing E‐modulus for the 40 μm fibers, whereas no significant change could be noticed in the 10 μm fibers. © 1995 John Wiley & Sons, Inc.