Rank dependence of organic sulfur functionalities in coal

Organic sulfur functionalities were characterized and quantified by atmospheric-pressure temperature-programmed reduction (AP-TPR). Nine coals were chosen to cover the entire rank range from subbituminous coal to anthracite. To be able to study the organic sulfur groups, the vitrinite concentrates w...

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Veröffentlicht in:Fuel (Guildford) 1997-04, Vol.76 (5), p.391-396
Hauptverfasser: Maes, Inge I., Gryglewicz, Grazyna, Machnikowska, Helena, Yperman, Jan, Franco, Dirk V., Mullens, Jules, Van Poucke, Lucien C.
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container_end_page 396
container_issue 5
container_start_page 391
container_title Fuel (Guildford)
container_volume 76
creator Maes, Inge I.
Gryglewicz, Grazyna
Machnikowska, Helena
Yperman, Jan
Franco, Dirk V.
Mullens, Jules
Van Poucke, Lucien C.
description Organic sulfur functionalities were characterized and quantified by atmospheric-pressure temperature-programmed reduction (AP-TPR). Nine coals were chosen to cover the entire rank range from subbituminous coal to anthracite. To be able to study the organic sulfur groups, the vitrinite concentrates were separated from each coal sample. The results confirm the larger amount of sulfide in low-rank coals. The amount of thiophenes generally increases with rank. Nevertheless, sulfur functionality distribution can vary from coal to coal even at the same rank.
doi_str_mv 10.1016/S0016-2361(97)85515-9
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source Elsevier ScienceDirect Journals
subjects Applied sciences
coal
Coal and derived products
Energy
Exact sciences and technology
Fuels
organic sulfur forms
rank
Structure, chemical and physical properties
title Rank dependence of organic sulfur functionalities in coal
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