Aliphatic and Aromatic C–H Bond Oxidation by High-Valent Manganese(IV)-Hydroxo Species

The strong C–H bond activation of hydrocarbons is a difficult reaction in environmental and biological chemistry. Herein, a high-valent manganese­(IV)-hydroxo complex, [MnIV(CHDAP-O)­(OH)]2+ (2), was synthesized and characterized by various physicochemical measurements, such as ultraviolet–visible (...

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Veröffentlicht in:	Journal of the American Chemical Society 2022-11, Vol.144 (45), p.20752-20762
Hauptverfasser:	Lee, Yujeong, Tripodi, Guilherme L., Jeong, Donghyun, Lee, Sunggi, Roithova, Jana, Cho, Jaeheung
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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