Total Synthesis of Alcyonolide

The total synthesis of alcyonolide, an antitumor xenicn diterpenoid, has been achieved. The inverse electron demand hetero-Diels–Alder reaction using a dienophile possessing an electron-withdrawing group provided the endo adduct which included a condensed lactone and dihydropyran rings with the desi...

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Veröffentlicht in:	Journal of organic chemistry 2022-11, Vol.87 (22), p.15492-15498
Hauptverfasser:	Fumiyama, Hitoshi, Takahashi, Arata, Suzuki, Yuma, Fujioka, Naoto, Matsumoto, Hirotake, Hosokawa, Seijiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Amides Cycloaddition Reaction Lactones Stereoisomerism
Online-Zugang:	Volltext
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