Investigation of Triangle Terthiophene and Hydroxyphenylbenzothiazole Configured Fluorescent Dye with a Triple Bond Bridge
A photochromic dye was constructed by incorporation of a carbon–carbon triple bond spaced triangle terthiophene skeleton and hydroxyphenylbenzothiazole. Regular photochromic behavior was investigated with alternated UV (254 nm) and visible light (≥ 400 nm) irradiation. The color of dye in solution c...
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| Veröffentlicht in: | Journal of fluorescence 2023, Vol.33 (1), p.153-159 |
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| creator | Ji, Guangqian Hou, Qiaozhi Zhang, Junna Li, Xiaochuan |
| description | A photochromic dye was constructed by incorporation of a carbon–carbon triple bond spaced triangle terthiophene skeleton and hydroxyphenylbenzothiazole. Regular photochromic behavior was investigated with alternated UV (254 nm) and visible light (≥ 400 nm) irradiation. The color of dye in solution can be cycled between pink and colorless. Additionally, the dye solution strongly fluoresces in THF with the absolute quantum yield (QY) being 0.56. When irradiation with 254 nm light, the emissive solution can be effectively quenched to photo-stationary sate (
Φ
= 0.05). An emission “on–off” cycle could be established based on the UV/visible light irradiation cycle. The photochromic dye also exhibits good photo- and thermal-stability at room temperature. The emission decay profile indicates typical single component character with the fluorescence lifetime being 6.68 ns. The emission color was determined by the CIE 1931 coordinates of
x
= 0.14,
y
= 0.25 in the blue region. |
| doi_str_mv | 10.1007/s10895-022-03049-3 |
| format | Article |
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Φ
= 0.05). An emission “on–off” cycle could be established based on the UV/visible light irradiation cycle. The photochromic dye also exhibits good photo- and thermal-stability at room temperature. The emission decay profile indicates typical single component character with the fluorescence lifetime being 6.68 ns. The emission color was determined by the CIE 1931 coordinates of
x
= 0.14,
y
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Φ
= 0.05). An emission “on–off” cycle could be established based on the UV/visible light irradiation cycle. The photochromic dye also exhibits good photo- and thermal-stability at room temperature. The emission decay profile indicates typical single component character with the fluorescence lifetime being 6.68 ns. The emission color was determined by the CIE 1931 coordinates of
x
= 0.14,
y
= 0.25 in the blue region.</description><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Biological and Medical Physics</subject><subject>Biomedical and Life Sciences</subject><subject>Biomedicine</subject><subject>Biophysics</subject><subject>Biotechnology</subject><subject>Carbon</subject><subject>Color</subject><subject>Emission</subject><subject>Fluorescent dyes</subject><subject>Light irradiation</subject><subject>Photochromism</subject><subject>Room temperature</subject><issn>1053-0509</issn><issn>1573-4994</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kU9v1DAQxS0Eon_gC3BAlrhwCR3bcWwf6dLSSpW4LGfLSeysq6y92AmQ_fR4uwWkHnqy5fm9NzN-CL0j8IkAiItMQCpeAaUVMKhVxV6gU8IFq2ql6pflDpxVwEGdoLOc7wFAyVq-RiesYUTWRJyi_W34afPkBzP5GHB0eJ28CcNo8dqmaePjbmODxSb0-GbpU_y9HB6WsbVhH0vd7GNhVzE4P8zJ9vh6nGOyubNhwl8Wi3_5aYPNwXZXwMtYjC6T7wf7Br1yZsz27eN5jr5fX61XN9Xdt6-3q893VceAT5UxfQvG8bbpZCMpNQ2vHbWs7hU1CpqOSkfBcUFE20ouGwPcFGXfCWe4bNk5-nj03aX4Yy7L6q0v442jCTbOWVPBykcJAqqgH56g93FOoUxXKEEaUVNJC0WPVJdizsk6vUt-a9KiCehDMvqYjC7J6IdkNCui94_Wc7u1_T_J3ygKwI5ALqUw2PS_9zO2fwAVV5rM</recordid><startdate>2023</startdate><enddate>2023</enddate><creator>Ji, Guangqian</creator><creator>Hou, Qiaozhi</creator><creator>Zhang, Junna</creator><creator>Li, Xiaochuan</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>2023</creationdate><title>Investigation of Triangle Terthiophene and Hydroxyphenylbenzothiazole Configured Fluorescent Dye with a Triple Bond Bridge</title><author>Ji, Guangqian ; Hou, Qiaozhi ; Zhang, Junna ; Li, Xiaochuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c305t-aadb0af5b6c86822a654f2e34d92a906c28f20f5717bb8586a05a305dc7fa58b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Biological and Medical Physics</topic><topic>Biomedical and Life Sciences</topic><topic>Biomedicine</topic><topic>Biophysics</topic><topic>Biotechnology</topic><topic>Carbon</topic><topic>Color</topic><topic>Emission</topic><topic>Fluorescent dyes</topic><topic>Light irradiation</topic><topic>Photochromism</topic><topic>Room temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ji, Guangqian</creatorcontrib><creatorcontrib>Hou, Qiaozhi</creatorcontrib><creatorcontrib>Zhang, Junna</creatorcontrib><creatorcontrib>Li, Xiaochuan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of fluorescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ji, Guangqian</au><au>Hou, Qiaozhi</au><au>Zhang, Junna</au><au>Li, Xiaochuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of Triangle Terthiophene and Hydroxyphenylbenzothiazole Configured Fluorescent Dye with a Triple Bond Bridge</atitle><jtitle>Journal of fluorescence</jtitle><stitle>J Fluoresc</stitle><addtitle>J Fluoresc</addtitle><date>2023</date><risdate>2023</risdate><volume>33</volume><issue>1</issue><spage>153</spage><epage>159</epage><pages>153-159</pages><issn>1053-0509</issn><eissn>1573-4994</eissn><abstract>A photochromic dye was constructed by incorporation of a carbon–carbon triple bond spaced triangle terthiophene skeleton and hydroxyphenylbenzothiazole. Regular photochromic behavior was investigated with alternated UV (254 nm) and visible light (≥ 400 nm) irradiation. The color of dye in solution can be cycled between pink and colorless. Additionally, the dye solution strongly fluoresces in THF with the absolute quantum yield (QY) being 0.56. When irradiation with 254 nm light, the emissive solution can be effectively quenched to photo-stationary sate (
Φ
= 0.05). An emission “on–off” cycle could be established based on the UV/visible light irradiation cycle. The photochromic dye also exhibits good photo- and thermal-stability at room temperature. The emission decay profile indicates typical single component character with the fluorescence lifetime being 6.68 ns. The emission color was determined by the CIE 1931 coordinates of
x
= 0.14,
y
= 0.25 in the blue region.</abstract><cop>New York</cop><pub>Springer US</pub><pmid>36318417</pmid><doi>10.1007/s10895-022-03049-3</doi><tpages>7</tpages></addata></record> |
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| subjects | Analytical Chemistry Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Carbon Color Emission Fluorescent dyes Light irradiation Photochromism Room temperature |
| title | Investigation of Triangle Terthiophene and Hydroxyphenylbenzothiazole Configured Fluorescent Dye with a Triple Bond Bridge |
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