Native Amide‐Directed C(sp3)−H Amidation Enabled by Electron‐Deficient RhIII Catalyst and Electron‐Deficient 2‐Pyridone Ligand

Trivalent group‐9 metal catalysts with a cyclopentadienyl‐type ligand (CpMIII; M=Co, Rh, Ir, Cp=cyclopentadienyl) have been widely used for directed C−H functionalizations, albeit that their application to challenging C(sp3)−H functionalizations suffers from the limitations of the available directin...

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Veröffentlicht in:	Angewandte Chemie International Edition 2022-12, Vol.61 (52), p.e202213659-n/a
Hauptverfasser:	Wakikawa, Takumi, Sekine, Daichi, Murata, Yuta, Bunno, Youka, Kojima, Masahiro, Nagashima, Yuki, Tanaka, Ken, Yoshino, Tatsuhiko, Matsunaga, Shigeki
Format:	Artikel
Sprache:	eng
Schlagworte:	2-Pyridone Amide Catalysts C−H Activation Dioxazolone Electrons Heavy metals Ligands Rhodium Substrates
Online-Zugang:	Volltext
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