Three-Input Logic AND Gate Drives Sequential Three-Step Catalysis by Parallel Activation of H+ and Ag+ as a Catalyst Duo

Three-Input Logic AND Gate Drives Sequential Three-Step Catalysis by Parallel Activation of H+ and Ag+ as a Catalyst Duo

Boolean operations with multiple catalysts as output are yet unknown using molecular logic. The issue is solved using a two-component ensemble, composed of a receptor and rotaxane, which acts as a three-input AND gate with a dual catalytic output. Actuation of the ensemble gate by the stoichiometric...

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Veröffentlicht in:Inorganic chemistry 2022-10, Vol.61 (43), p.17007-17011
Hauptverfasser: Kundu, Sohom, Mondal, Debabrata, Rajasekaran, Vishnu Verman, Goswami, Abir, Schmittel, Michael
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container_end_page 17011
container_issue 43
container_start_page 17007
container_title Inorganic chemistry
container_volume 61
creator Kundu, Sohom
Mondal, Debabrata
Rajasekaran, Vishnu Verman
Goswami, Abir
Schmittel, Michael
description Boolean operations with multiple catalysts as output are yet unknown using molecular logic. The issue is solved using a two-component ensemble, composed of a receptor and rotaxane, which acts as a three-input AND gate with a dual catalytic output. Actuation of the ensemble gate by the stoichiometric addition of metal ions (Ag+ and Cd2+) and 2,2,2-trifluoroacetic acid generated in the (1,1,1) truth table state a catalyst duo that synergistically enabled a three-step reaction, furnishing a dihydroisoquinoline as the output of a three-input logic AND gate operation.
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title Three-Input Logic AND Gate Drives Sequential Three-Step Catalysis by Parallel Activation of H+ and Ag+ as a Catalyst Duo
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