Stabilizing large pores in a flexible metal–organic framework via chemical cross-linking
A barrier to the isoreticular expansion of flexible metal–organic frameworks is their complex breathing behavior, which can lead to pore closure upon solvent exchange and removal. Here we show that chemical cross-linking stabilizes the open form of a flexible aluminum framework with large 17 Å pores...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-11, Vol.58 (88), p.12361-12364 |
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| container_end_page | 12364 |
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| container_issue | 88 |
| container_start_page | 12361 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 58 |
| creator | Rollins, Devin S. Geary, Jackson Wong, Andy H. Xiao, Dianne J. |
| description | A barrier to the isoreticular expansion of flexible metal–organic frameworks is their complex breathing behavior, which can lead to pore closure upon solvent exchange and removal. Here we show that chemical cross-linking stabilizes the open form of a flexible aluminum framework with large 17 Å pores. |
| doi_str_mv | 10.1039/d2cc04829a |
| format | Article |
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2022-11, Vol.58 (88), p.12361-12364 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2726923014 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aluminum Crosslinking Metal-organic frameworks |
| title | Stabilizing large pores in a flexible metal–organic framework via chemical cross-linking |
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