Unusual Diradical Intermediates in Ozonolysis of Alkenes: A Combined Theoretical and Synchrotron Radiation Photoionization Mass Spectrometric Study on Ozonolysis of Alkyl Vinyl Ethers

Calculations and experiments were conducted on ozonolysis of ethyl vinyl ether (EVE) and butyl vinyl ether to identify an unconventional diradical intermediate generated from the O–O bond cleavage of primary ozonide. The diradical can undergo a H atom shifting process that yields keto-hydroperoxide...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2022-11, Vol.126 (43), p.8021-8027
Hauptverfasser:	Fan, Hanlin, Ma, Jun, Zhu, Long, Liu, Bingzhi, Liu, Fuyi, Shan, Xiaobin, Wang, Zhandong, Wang, Liming
Format:	Artikel
Sprache:	eng
Schlagworte:	A: Aerosols Environmental and Atmospheric Chemistry Astrochemistry
Online-Zugang:	Volltext
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