The effect of deuteration on the stabilities of cis-polyacetylene and polystyrene
Differential scanning calorimetry (d.s.c.) confirms the greater stability of deuterated polystyrene compared to normal polystyrene with respect to oxidation in air. However, the same technique shows that the stability of deuterated cis-polyacetylene with respect to oxidation in air is no better than...
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| Veröffentlicht in: | Polymer (Guilford) 1994-01, Vol.35 (9), p.1952-1956 |
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| container_end_page | 1956 |
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| container_issue | 9 |
| container_start_page | 1952 |
| container_title | Polymer (Guilford) |
| container_volume | 35 |
| creator | Jessop, Philip G Morris, Robert H Azizian, Hormoz |
| description | Differential scanning calorimetry (d.s.c.) confirms the greater stability of deuterated polystyrene compared to normal polystyrene with respect to oxidation in air. However, the same technique shows that the stability of deuterated
cis-polyacetylene with respect to oxidation in air is no better than that of normal
cis-polyacetylene. Our d.s.c. results also suggest that there may be a weak isotope effect for the hydrogen migration reaction under nitrogen but not for the isomerization of deuterated
cis-polyacetylene to the
trans isomers. |
| doi_str_mv | 10.1016/0032-3861(94)90987-3 |
| format | Article |
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cis-polyacetylene with respect to oxidation in air is no better than that of normal
cis-polyacetylene. Our d.s.c. results also suggest that there may be a weak isotope effect for the hydrogen migration reaction under nitrogen but not for the isomerization of deuterated
cis-polyacetylene to the
trans isomers.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/0032-3861(94)90987-3</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; deuteration ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; polyacetylene ; polystyrene ; Properties and characterization ; Thermal and thermodynamic properties</subject><ispartof>Polymer (Guilford), 1994-01, Vol.35 (9), p.1952-1956</ispartof><rights>1994</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-9e5e41d60fde5546d5d31f89a51d5e575d1c3c5bb53f9cfdba4d919007bdd2a03</citedby><cites>FETCH-LOGICAL-c364t-9e5e41d60fde5546d5d31f89a51d5e575d1c3c5bb53f9cfdba4d919007bdd2a03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0032-3861(94)90987-3$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27911,27912,45982</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4016423$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Jessop, Philip G</creatorcontrib><creatorcontrib>Morris, Robert H</creatorcontrib><creatorcontrib>Azizian, Hormoz</creatorcontrib><title>The effect of deuteration on the stabilities of cis-polyacetylene and polystyrene</title><title>Polymer (Guilford)</title><description>Differential scanning calorimetry (d.s.c.) confirms the greater stability of deuterated polystyrene compared to normal polystyrene with respect to oxidation in air. However, the same technique shows that the stability of deuterated
cis-polyacetylene with respect to oxidation in air is no better than that of normal
cis-polyacetylene. Our d.s.c. results also suggest that there may be a weak isotope effect for the hydrogen migration reaction under nitrogen but not for the isomerization of deuterated
cis-polyacetylene to the
trans isomers.</description><subject>Applied sciences</subject><subject>deuteration</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>polyacetylene</subject><subject>polystyrene</subject><subject>Properties and characterization</subject><subject>Thermal and thermodynamic properties</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-Aw89iOihms-2uQiy-AULIqznkCYTjHTbNckK_femruxRCIRMnneGeRA6J_iGYFLdYsxoyZqKXEl-LbFs6pIdoBlpalZSKskhmu2RY3QS4yfGmArKZ-ht9QEFOAcmFYMrLGwTBJ380Bf5pPwZk25955OHOBHGx3IzdKM2kMYOeih0b4upEtMY8vsUHTndRTj7u-fo_fFhtXgul69PL4v7ZWlYxVMpQQAntsLOghC8ssIy4hqpBbECRC0sMcyIthXMSeNsq7mVRGJct9ZSjdkcXe76bsLwtYWY1NpHA12nexi2UdGaVqwRMoN8B5owxBjAqU3wax1GRbCa_KlJjprkKMnVrz_Fcuzir7-ORncu6D7vvs_yHOR0wu52GORdvz0EFY2H3oD1IUtVdvD_z_kB9N-FBw</recordid><startdate>19940101</startdate><enddate>19940101</enddate><creator>Jessop, Philip G</creator><creator>Morris, Robert H</creator><creator>Azizian, Hormoz</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19940101</creationdate><title>The effect of deuteration on the stabilities of cis-polyacetylene and polystyrene</title><author>Jessop, Philip G ; Morris, Robert H ; Azizian, Hormoz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-9e5e41d60fde5546d5d31f89a51d5e575d1c3c5bb53f9cfdba4d919007bdd2a03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>Applied sciences</topic><topic>deuteration</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>polyacetylene</topic><topic>polystyrene</topic><topic>Properties and characterization</topic><topic>Thermal and thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jessop, Philip G</creatorcontrib><creatorcontrib>Morris, Robert H</creatorcontrib><creatorcontrib>Azizian, Hormoz</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jessop, Philip G</au><au>Morris, Robert H</au><au>Azizian, Hormoz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of deuteration on the stabilities of cis-polyacetylene and polystyrene</atitle><jtitle>Polymer (Guilford)</jtitle><date>1994-01-01</date><risdate>1994</risdate><volume>35</volume><issue>9</issue><spage>1952</spage><epage>1956</epage><pages>1952-1956</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>Differential scanning calorimetry (d.s.c.) confirms the greater stability of deuterated polystyrene compared to normal polystyrene with respect to oxidation in air. However, the same technique shows that the stability of deuterated
cis-polyacetylene with respect to oxidation in air is no better than that of normal
cis-polyacetylene. Our d.s.c. results also suggest that there may be a weak isotope effect for the hydrogen migration reaction under nitrogen but not for the isomerization of deuterated
cis-polyacetylene to the
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| fulltext | fulltext |
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| ispartof | Polymer (Guilford), 1994-01, Vol.35 (9), p.1952-1956 |
| issn | 0032-3861 1873-2291 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_27263859 |
| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | Applied sciences deuteration Exact sciences and technology Organic polymers Physicochemistry of polymers polyacetylene polystyrene Properties and characterization Thermal and thermodynamic properties |
| title | The effect of deuteration on the stabilities of cis-polyacetylene and polystyrene |
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