Synthesis, characterization and semiconducting properties of solid solutions with rutile structure
A new family of oxides Ti 3(1−x)M xM′ 2xO 6 (0.1 ≤ x ≤ 0.3) is obtained by partial substitution of Ti by M (Co or Ni) and M′ (Sb or Nb) elements in the rutile structure. These solid solutions develop previous works concerting related systems with disordered cation distribution, which show semiconduc...
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| Veröffentlicht in: | Materials research bulletin 1994, Vol.29 (8), p.861-869 |
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| creator | Belloch, J.M. Isasi, J. López, M.L. Veiga, M.L. Pico, C. |
| description | A new family of oxides Ti
3(1−x)M
xM′
2xO
6 (0.1 ≤ x ≤ 0.3) is obtained by partial substitution of Ti by M (Co or Ni) and M′ (Sb or Nb) elements in the rutile structure. These solid solutions develop previous works concerting related systems with disordered cation distribution, which show semiconductivity properties. The activation energies lies between 0.5 and 1.1 eV and the Seebeck's effect suggests different charge carriers depending on the nature of the divalent cation. Thus, cobalt compounds are p-type semiconductors where as nickel compounds are of n-type. Magnetic susceptibility data agree with the proposed structural model. |
| doi_str_mv | 10.1016/0025-5408(94)90006-X |
| format | Article |
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3(1−x)M
xM′
2xO
6 (0.1 ≤ x ≤ 0.3) is obtained by partial substitution of Ti by M (Co or Ni) and M′ (Sb or Nb) elements in the rutile structure. These solid solutions develop previous works concerting related systems with disordered cation distribution, which show semiconductivity properties. The activation energies lies between 0.5 and 1.1 eV and the Seebeck's effect suggests different charge carriers depending on the nature of the divalent cation. Thus, cobalt compounds are p-type semiconductors where as nickel compounds are of n-type. Magnetic susceptibility data agree with the proposed structural model.</description><identifier>ISSN: 0025-5408</identifier><identifier>EISSN: 1873-4227</identifier><identifier>DOI: 10.1016/0025-5408(94)90006-X</identifier><identifier>CODEN: MRBUAC</identifier><language>eng</language><publisher>London: Elsevier Ltd</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Conductivity phenomena in semiconductors and insulators ; Electronic transport in condensed matter ; Exact sciences and technology ; Inorganic compounds ; Low-field transport and mobility; piezoresistance ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; Water, oxides, hydroxides, peroxides</subject><ispartof>Materials research bulletin, 1994, Vol.29 (8), p.861-869</ispartof><rights>1994</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-4b5337dd7ad2e286a1037c91dc8f5c78ee3223ba13d133f595d6e782bab86c7d3</citedby><cites>FETCH-LOGICAL-c364t-4b5337dd7ad2e286a1037c91dc8f5c78ee3223ba13d133f595d6e782bab86c7d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/002554089490006X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,4010,27900,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4169533$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Belloch, J.M.</creatorcontrib><creatorcontrib>Isasi, J.</creatorcontrib><creatorcontrib>López, M.L.</creatorcontrib><creatorcontrib>Veiga, M.L.</creatorcontrib><creatorcontrib>Pico, C.</creatorcontrib><title>Synthesis, characterization and semiconducting properties of solid solutions with rutile structure</title><title>Materials research bulletin</title><description>A new family of oxides Ti
3(1−x)M
xM′
2xO
6 (0.1 ≤ x ≤ 0.3) is obtained by partial substitution of Ti by M (Co or Ni) and M′ (Sb or Nb) elements in the rutile structure. These solid solutions develop previous works concerting related systems with disordered cation distribution, which show semiconductivity properties. The activation energies lies between 0.5 and 1.1 eV and the Seebeck's effect suggests different charge carriers depending on the nature of the divalent cation. Thus, cobalt compounds are p-type semiconductors where as nickel compounds are of n-type. Magnetic susceptibility data agree with the proposed structural model.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Conductivity phenomena in semiconductors and insulators</subject><subject>Electronic transport in condensed matter</subject><subject>Exact sciences and technology</subject><subject>Inorganic compounds</subject><subject>Low-field transport and mobility; piezoresistance</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Water, oxides, hydroxides, peroxides</subject><issn>0025-5408</issn><issn>1873-4227</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNp9kF9LHTEQxUOp4K36DXzIQykV3Jp_m-y-CCLaFgQfrOBbyCazvSl7d6-ZrGI_vdle8bEvMwz8zsycQ8gxZ9844_qMMVFXtWLN11adtIwxXT18ICveGFkpIcxHsnpH9sknxD-FUY0xK9LdvYx5DRjxlPq1S85nSPGvy3EaqRsDRdhEP41h9jmOv-k2TVtIOQLSqac4DTEsdV54pM8xr2kqwwAUcyqaOcEh2evdgHD01g_I_fXVr8sf1c3t95-XFzeVl1rlSnW1lCYE44IA0WjHmTS-5cE3fe1NAyCFkJ3jMnAp-7qtgwbTiM51jfYmyAPyZbe3_Pg4A2a7iehhGNwI04xWGKE506KAagf6NCEm6O02xY1LL5YzuwRql7TskpZtlf0XqH0oss9v-x16N_TJjT7iu1Zx3RYHBTvfYVC8PkVIFn2E0UOICXy2YYr_v_MKOASMbg</recordid><startdate>1994</startdate><enddate>1994</enddate><creator>Belloch, J.M.</creator><creator>Isasi, J.</creator><creator>López, M.L.</creator><creator>Veiga, M.L.</creator><creator>Pico, C.</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1994</creationdate><title>Synthesis, characterization and semiconducting properties of solid solutions with rutile structure</title><author>Belloch, J.M. ; Isasi, J. ; López, M.L. ; Veiga, M.L. ; Pico, C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-4b5337dd7ad2e286a1037c91dc8f5c78ee3223ba13d133f595d6e782bab86c7d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Conductivity phenomena in semiconductors and insulators</topic><topic>Electronic transport in condensed matter</topic><topic>Exact sciences and technology</topic><topic>Inorganic compounds</topic><topic>Low-field transport and mobility; piezoresistance</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Water, oxides, hydroxides, peroxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Belloch, J.M.</creatorcontrib><creatorcontrib>Isasi, J.</creatorcontrib><creatorcontrib>López, M.L.</creatorcontrib><creatorcontrib>Veiga, M.L.</creatorcontrib><creatorcontrib>Pico, C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials research bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Belloch, J.M.</au><au>Isasi, J.</au><au>López, M.L.</au><au>Veiga, M.L.</au><au>Pico, C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, characterization and semiconducting properties of solid solutions with rutile structure</atitle><jtitle>Materials research bulletin</jtitle><date>1994</date><risdate>1994</risdate><volume>29</volume><issue>8</issue><spage>861</spage><epage>869</epage><pages>861-869</pages><issn>0025-5408</issn><eissn>1873-4227</eissn><coden>MRBUAC</coden><abstract>A new family of oxides Ti
3(1−x)M
xM′
2xO
6 (0.1 ≤ x ≤ 0.3) is obtained by partial substitution of Ti by M (Co or Ni) and M′ (Sb or Nb) elements in the rutile structure. These solid solutions develop previous works concerting related systems with disordered cation distribution, which show semiconductivity properties. The activation energies lies between 0.5 and 1.1 eV and the Seebeck's effect suggests different charge carriers depending on the nature of the divalent cation. Thus, cobalt compounds are p-type semiconductors where as nickel compounds are of n-type. Magnetic susceptibility data agree with the proposed structural model.</abstract><cop>London</cop><cop>Amsterdam</cop><pub>Elsevier Ltd</pub><doi>10.1016/0025-5408(94)90006-X</doi><tpages>9</tpages></addata></record> |
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| ispartof | Materials research bulletin, 1994, Vol.29 (8), p.861-869 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Conductivity phenomena in semiconductors and insulators Electronic transport in condensed matter Exact sciences and technology Inorganic compounds Low-field transport and mobility piezoresistance Physics Structure of solids and liquids crystallography Structure of specific crystalline solids Water, oxides, hydroxides, peroxides |
| title | Synthesis, characterization and semiconducting properties of solid solutions with rutile structure |
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