Ceramic joining through reactive wetting of alumina with calcium aluminate refractory cements

Compositions in CaO-Al2O3 system have been prepared by gel-to-crystallite conversion method. Reactive powders of 1 : 2, 1 : 1, 2 : 1 and 3 : 1 of CaO and2O3 compositions were obtained by calcining the product at 800–1200°C. Fine grained powders were used as refractory cement for joining alumina cera...

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Veröffentlicht in:Bulletin of materials science 2000-08, Vol.23 (4), p.243-248
Hauptverfasser: Geetha, K., Umarji, A. M., Kutty, T. R. N.
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Kutty, T. R. N.
description Compositions in CaO-Al2O3 system have been prepared by gel-to-crystallite conversion method. Reactive powders of 1 : 2, 1 : 1, 2 : 1 and 3 : 1 of CaO and2O3 compositions were obtained by calcining the product at 800–1200°C. Fine grained powders were used as refractory cement for joining alumina ceramics. An optimum temperature of 1450°C for 4 h produced joints of satisfactory strength. The microstructure and X-ray phase analysis of the fractured joint surface clearly indicate reactive wetting of the alumina ceramics. This wetting enhances the joining of alumina substrates and can be attributed to the formation of Ca12Al14O33 liquid phase. The results are explained by using CaO-Al2O3 phase diagram.
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subjects Aluminum oxide
Calcium aluminate
Calcium oxide
Ceramic cements
Ceramics
Composition
Conversion
Crystallites
Joining
Liquid phases
Phase diagrams
Refractory cements
Substrates
Wetting
title Ceramic joining through reactive wetting of alumina with calcium aluminate refractory cements
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