Chlorine and nitrogen doped carbon grown from a tetrachloroethylene and nitrogen feedstock

Chlorine and nitrogen doped carbon has been grown by chemical vapor deposition of tetrachloroethylene and nitrogen. The film is predominantly carbon (90 at.%) in an amorphous state, but does contain some chlorine terminated carbon nitride aromatic rings, as determined by 13C NMR. The small amount of...

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Veröffentlicht in:Solid state communications 2000-01, Vol.114 (4), p.193-196
Hauptverfasser: Lin, S.-H, Braddock-Wilking, J, Feldman, B.J
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Braddock-Wilking, J
Feldman, B.J
description Chlorine and nitrogen doped carbon has been grown by chemical vapor deposition of tetrachloroethylene and nitrogen. The film is predominantly carbon (90 at.%) in an amorphous state, but does contain some chlorine terminated carbon nitride aromatic rings, as determined by 13C NMR. The small amount of chlorine present in the material is inadequate to terminate most of the dangling bonds, leading to a large absorption below the optical band gap, but large enough to significantly increase the optical band gap. And the infrared absorption is dominated by an intense line at 1270 cm −1, which is interpreted as due to the amorphous carbon network.
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source ScienceDirect Journals (5 years ago - present)
subjects A. Disordered systems
A. Nanostructures
B. Chemical synthesis. D. Optical properties
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
E. Nuclear resonances
Exact sciences and technology
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Physics
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
title Chlorine and nitrogen doped carbon grown from a tetrachloroethylene and nitrogen feedstock
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