Synthesis of Vinylene‐Linked Thiopyrylium‐, Pyrylium‐, and Pyridinium‐Based Covalent Organic Frameworks by Acid‐Catalyzed Aldol Condensation
The development of new vinylene‐linked covalent organic frameworks (COFs) with special ionic structure and high stability is challenging. Herein, we report a facile, general method for constructing ionic vinylene‐linked thiopyrylium‐based COFs from 2,4,6‐trimethylpyrylium tetrafluoroborate and other...
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| Veröffentlicht in: | Chemistry : a European journal 2023-01, Vol.29 (1), p.e202202787-n/a |
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| container_title | Chemistry : a European journal |
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| creator | Ji, Haifeng Yan, Gaojie Zou, Peng Wang, Han Li, Mengke Feng, Yi Qu, Xiongwei Geng, Dongling Shi, Jingjing Zhang, Xiaojie |
| description | The development of new vinylene‐linked covalent organic frameworks (COFs) with special ionic structure and high stability is challenging. Herein, we report a facile, general method for constructing ionic vinylene‐linked thiopyrylium‐based COFs from 2,4,6‐trimethylpyrylium tetrafluoroborate and other common reagents by means of acid‐catalyzed Aldol condensation. Besides, pyrylium‐, and pyridinium‐based COFs also can be prepared from the same monomer under slightly different reaction conditions. The COFs exhibited uniform nanofibrous morphologies with excellent crystallinities, special ionic structures, well‐defined nanochannels, and high specific surface areas.
Vinylene‐linked thiopyrylium‐based covalent organic frameworks (COFs) were synthesized from 2,4,6‐trimethylpyrylium tetrafluoroborate and other common reagents by means of acid‐catalyzed Aldol condensation. Besides, pyrylium‐, and pyridinium‐based COFs also can be prepared from the same monomer under slightly different reaction conditions. |
| doi_str_mv | 10.1002/chem.202202787 |
| format | Article |
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Vinylene‐linked thiopyrylium‐based covalent organic frameworks (COFs) were synthesized from 2,4,6‐trimethylpyrylium tetrafluoroborate and other common reagents by means of acid‐catalyzed Aldol condensation. Besides, pyrylium‐, and pyridinium‐based COFs also can be prepared from the same monomer under slightly different reaction conditions.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.202202787</identifier><identifier>PMID: 36196504</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Aldehydes ; Aldol condensation ; Chemistry ; CO2 adsorption ; covalent organic framework ; Nanochannels ; Pyridinium ; Reagents ; Structural stability ; thiopyrylium-based ; vinylene-linked</subject><ispartof>Chemistry : a European journal, 2023-01, Vol.29 (1), p.e202202787-n/a</ispartof><rights>2022 Wiley‐VCH GmbH</rights><rights>2022 Wiley-VCH GmbH.</rights><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3737-dc86466738446a31cc538dd75360f95a74e65ede7cf4a607494913af28562d833</citedby><cites>FETCH-LOGICAL-c3737-dc86466738446a31cc538dd75360f95a74e65ede7cf4a607494913af28562d833</cites><orcidid>0000-0002-8204-4845</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.202202787$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.202202787$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36196504$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ji, Haifeng</creatorcontrib><creatorcontrib>Yan, Gaojie</creatorcontrib><creatorcontrib>Zou, Peng</creatorcontrib><creatorcontrib>Wang, Han</creatorcontrib><creatorcontrib>Li, Mengke</creatorcontrib><creatorcontrib>Feng, Yi</creatorcontrib><creatorcontrib>Qu, Xiongwei</creatorcontrib><creatorcontrib>Geng, Dongling</creatorcontrib><creatorcontrib>Shi, Jingjing</creatorcontrib><creatorcontrib>Zhang, Xiaojie</creatorcontrib><title>Synthesis of Vinylene‐Linked Thiopyrylium‐, Pyrylium‐, and Pyridinium‐Based Covalent Organic Frameworks by Acid‐Catalyzed Aldol Condensation</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>The development of new vinylene‐linked covalent organic frameworks (COFs) with special ionic structure and high stability is challenging. Herein, we report a facile, general method for constructing ionic vinylene‐linked thiopyrylium‐based COFs from 2,4,6‐trimethylpyrylium tetrafluoroborate and other common reagents by means of acid‐catalyzed Aldol condensation. Besides, pyrylium‐, and pyridinium‐based COFs also can be prepared from the same monomer under slightly different reaction conditions. The COFs exhibited uniform nanofibrous morphologies with excellent crystallinities, special ionic structures, well‐defined nanochannels, and high specific surface areas.
Vinylene‐linked thiopyrylium‐based covalent organic frameworks (COFs) were synthesized from 2,4,6‐trimethylpyrylium tetrafluoroborate and other common reagents by means of acid‐catalyzed Aldol condensation. Besides, pyrylium‐, and pyridinium‐based COFs also can be prepared from the same monomer under slightly different reaction conditions.</description><subject>Aldehydes</subject><subject>Aldol condensation</subject><subject>Chemistry</subject><subject>CO2 adsorption</subject><subject>covalent organic framework</subject><subject>Nanochannels</subject><subject>Pyridinium</subject><subject>Reagents</subject><subject>Structural stability</subject><subject>thiopyrylium-based</subject><subject>vinylene-linked</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS1ERYfCliWKxIYFGez4L1kOUUsrDSoShW3k2jeMW8ee2glVWPEIrHhAngSPphTEBulKV_foO0dXOgg9I3hJMK5e6w0MywpXeWQtH6AF4RUpqRT8IVrghslScNocoscpXWGMG0HpI3RIBWkEx2yBfnyY_biBZFMR-uKT9bMDDz-_fV9bfw2muNjYsJ3j7Ow0ZPVV8f7vQ3mzE6yxfi-9USmb2vBF5ZixOI-flbe6OIlqgNsQr1NxORcrbU1mWzUqN3_N_MqZ4LLLG_BJjTb4J-igVy7B07t9hD6eHF-0p-X6_O1Zu1qXmkoqS6NrwYSQtGZMKEq05rQ2RnIqcN9wJRkIDgak7pkSWLKGNYSqvqq5qExN6RF6uc_dxnAzQRq7wSYNzikPYUpdJSsiqMh0Rl_8g16FKfr8XabyM4xLvKOWe0rHkFKEvttGO6g4dwR3u8a6XWPdfWPZ8PwudrocwNzjvyvKQLMHbq2D-T9xXXt6_O5P-C-aQKhJ</recordid><startdate>20230102</startdate><enddate>20230102</enddate><creator>Ji, Haifeng</creator><creator>Yan, Gaojie</creator><creator>Zou, Peng</creator><creator>Wang, Han</creator><creator>Li, Mengke</creator><creator>Feng, Yi</creator><creator>Qu, Xiongwei</creator><creator>Geng, Dongling</creator><creator>Shi, Jingjing</creator><creator>Zhang, Xiaojie</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-8204-4845</orcidid></search><sort><creationdate>20230102</creationdate><title>Synthesis of Vinylene‐Linked Thiopyrylium‐, Pyrylium‐, and Pyridinium‐Based Covalent Organic Frameworks by Acid‐Catalyzed Aldol Condensation</title><author>Ji, Haifeng ; Yan, Gaojie ; Zou, Peng ; Wang, Han ; Li, Mengke ; Feng, Yi ; Qu, Xiongwei ; Geng, Dongling ; Shi, Jingjing ; Zhang, Xiaojie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3737-dc86466738446a31cc538dd75360f95a74e65ede7cf4a607494913af28562d833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aldehydes</topic><topic>Aldol condensation</topic><topic>Chemistry</topic><topic>CO2 adsorption</topic><topic>covalent organic framework</topic><topic>Nanochannels</topic><topic>Pyridinium</topic><topic>Reagents</topic><topic>Structural stability</topic><topic>thiopyrylium-based</topic><topic>vinylene-linked</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ji, Haifeng</creatorcontrib><creatorcontrib>Yan, Gaojie</creatorcontrib><creatorcontrib>Zou, Peng</creatorcontrib><creatorcontrib>Wang, Han</creatorcontrib><creatorcontrib>Li, Mengke</creatorcontrib><creatorcontrib>Feng, Yi</creatorcontrib><creatorcontrib>Qu, Xiongwei</creatorcontrib><creatorcontrib>Geng, Dongling</creatorcontrib><creatorcontrib>Shi, Jingjing</creatorcontrib><creatorcontrib>Zhang, Xiaojie</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ji, Haifeng</au><au>Yan, Gaojie</au><au>Zou, Peng</au><au>Wang, Han</au><au>Li, Mengke</au><au>Feng, Yi</au><au>Qu, Xiongwei</au><au>Geng, Dongling</au><au>Shi, Jingjing</au><au>Zhang, Xiaojie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Vinylene‐Linked Thiopyrylium‐, Pyrylium‐, and Pyridinium‐Based Covalent Organic Frameworks by Acid‐Catalyzed Aldol Condensation</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2023-01-02</date><risdate>2023</risdate><volume>29</volume><issue>1</issue><spage>e202202787</spage><epage>n/a</epage><pages>e202202787-n/a</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>The development of new vinylene‐linked covalent organic frameworks (COFs) with special ionic structure and high stability is challenging. Herein, we report a facile, general method for constructing ionic vinylene‐linked thiopyrylium‐based COFs from 2,4,6‐trimethylpyrylium tetrafluoroborate and other common reagents by means of acid‐catalyzed Aldol condensation. Besides, pyrylium‐, and pyridinium‐based COFs also can be prepared from the same monomer under slightly different reaction conditions. The COFs exhibited uniform nanofibrous morphologies with excellent crystallinities, special ionic structures, well‐defined nanochannels, and high specific surface areas.
Vinylene‐linked thiopyrylium‐based covalent organic frameworks (COFs) were synthesized from 2,4,6‐trimethylpyrylium tetrafluoroborate and other common reagents by means of acid‐catalyzed Aldol condensation. Besides, pyrylium‐, and pyridinium‐based COFs also can be prepared from the same monomer under slightly different reaction conditions.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>36196504</pmid><doi>10.1002/chem.202202787</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-8204-4845</orcidid></addata></record> |
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| subjects | Aldehydes Aldol condensation Chemistry CO2 adsorption covalent organic framework Nanochannels Pyridinium Reagents Structural stability thiopyrylium-based vinylene-linked |
| title | Synthesis of Vinylene‐Linked Thiopyrylium‐, Pyrylium‐, and Pyridinium‐Based Covalent Organic Frameworks by Acid‐Catalyzed Aldol Condensation |
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