A microbeam RBS analysis of low temperature direct-write inkjet deposited copper

Quantitative microbeam Rutherford backscattering (RBS) analysis with a 1.5 MeV 4 He + beam has determined limits on the purity of copper deposited on glass with a novel inkjet process. A tetravinyl silane tetrakisCu(I) 1,1,1,5,5,5-hexafluoroacetylacetonate (TVST[Cu]hfac) complex was heated to 70 °C...

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Veröffentlicht in:Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms Beam interactions with materials and atoms, 2002-04, Vol.188 (1), p.141-145
Hauptverfasser: Jeynes, C., Rozenberg, G.G., Speakman, S.P., Steinke, J.H.G.
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container_start_page 141
container_title Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms
container_volume 188
creator Jeynes, C.
Rozenberg, G.G.
Speakman, S.P.
Steinke, J.H.G.
description Quantitative microbeam Rutherford backscattering (RBS) analysis with a 1.5 MeV 4 He + beam has determined limits on the purity of copper deposited on glass with a novel inkjet process. A tetravinyl silane tetrakisCu(I) 1,1,1,5,5,5-hexafluoroacetylacetonate (TVST[Cu]hfac) complex was heated to 70 °C and jetted onto the glass substrate through a piezoelectric ceramic print head in droplets about 0.5 mm diameter. The substrate temperature was 150 °C. Solid well-formed deposits resulted which have a copper content greater than about 90% by weight. The RBS spectra were analysed objectively using the DataFurnace code, with the assumption that the deposit was CuO x , and the validity of different assumed values of x being tested. The assumptions and the errors of the analysis are critically evaluated.
doi_str_mv 10.1016/S0168-583X(01)01063-1
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subjects CVD
Electronics
Markov chain Monte Carlo
Organometallic
PCB
title A microbeam RBS analysis of low temperature direct-write inkjet deposited copper
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