Thin films of polyaniline–polyacrylic acid composite by chemical bath deposition
Polyaniline (PANI)–polyacrylic acid (PAA) composite thin films were deposited at room temperature on glass and polymethyl methacrylate substrates by introducing these into a freshly prepared chemical bath of HCl, PAA, aniline monomers and (NH 4) 2S 2O 8. Compared to the single PANI films, which were...
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| Veröffentlicht in: | Thin solid films 1999-06, Vol.347 (1), p.241-247 |
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| container_title | Thin solid films |
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| creator | Hu, Hailin Saniger, José M. Bañuelos, José G. |
| description | Polyaniline (PANI)–polyacrylic acid (PAA) composite thin films were deposited at room temperature on glass and polymethyl methacrylate substrates by introducing these into a freshly prepared chemical bath of HCl, PAA, aniline monomers and (NH
4)
2S
2O
8. Compared to the single PANI films, which were obtained from the same bath constitution but without PAA solution, the composite films showed a red shift at the maximum optical transmittance peak and a slightly lower electrical conductivity. Fourier transform infrared spectroscopy studies of the PANI composite thin films indicated the presence of the acid-base reaction product between PANI and PAA, as well as PAA molecule incorporation in the films. Atomic force microscopy analysis also showed morphologic and mechanical elasticity differences between the single PANI film the composite films deposited by the chemical bath method. |
| doi_str_mv | 10.1016/S0040-6090(99)00039-5 |
| format | Article |
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4)
2S
2O
8. Compared to the single PANI films, which were obtained from the same bath constitution but without PAA solution, the composite films showed a red shift at the maximum optical transmittance peak and a slightly lower electrical conductivity. Fourier transform infrared spectroscopy studies of the PANI composite thin films indicated the presence of the acid-base reaction product between PANI and PAA, as well as PAA molecule incorporation in the films. Atomic force microscopy analysis also showed morphologic and mechanical elasticity differences between the single PANI film the composite films deposited by the chemical bath method.</description><identifier>ISSN: 0040-6090</identifier><identifier>EISSN: 1879-2731</identifier><identifier>DOI: 10.1016/S0040-6090(99)00039-5</identifier><identifier>CODEN: THSFAP</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Applied sciences ; Atomic force microscopy ; Chemical bath deposition ; Composite thin films ; Exact sciences and technology ; Fourier transform infrared spectrum ; Optical absorption coefficient ; Organic polymers ; Physicochemistry of polymers ; Polyacrylic acid ; Polyaniline ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Thin solid films, 1999-06, Vol.347 (1), p.241-247</ispartof><rights>1999 Elsevier Science S.A.</rights><rights>1999 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c433t-4acb960a2341237925d883c6de2dc78360ce91d05efa9f6565848230147b62173</citedby><cites>FETCH-LOGICAL-c433t-4acb960a2341237925d883c6de2dc78360ce91d05efa9f6565848230147b62173</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0040-6090(99)00039-5$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1903344$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hu, Hailin</creatorcontrib><creatorcontrib>Saniger, José M.</creatorcontrib><creatorcontrib>Bañuelos, José G.</creatorcontrib><title>Thin films of polyaniline–polyacrylic acid composite by chemical bath deposition</title><title>Thin solid films</title><description>Polyaniline (PANI)–polyacrylic acid (PAA) composite thin films were deposited at room temperature on glass and polymethyl methacrylate substrates by introducing these into a freshly prepared chemical bath of HCl, PAA, aniline monomers and (NH
4)
2S
2O
8. Compared to the single PANI films, which were obtained from the same bath constitution but without PAA solution, the composite films showed a red shift at the maximum optical transmittance peak and a slightly lower electrical conductivity. Fourier transform infrared spectroscopy studies of the PANI composite thin films indicated the presence of the acid-base reaction product between PANI and PAA, as well as PAA molecule incorporation in the films. Atomic force microscopy analysis also showed morphologic and mechanical elasticity differences between the single PANI film the composite films deposited by the chemical bath method.</description><subject>Applied sciences</subject><subject>Atomic force microscopy</subject><subject>Chemical bath deposition</subject><subject>Composite thin films</subject><subject>Exact sciences and technology</subject><subject>Fourier transform infrared spectrum</subject><subject>Optical absorption coefficient</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polyacrylic acid</subject><subject>Polyaniline</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0040-6090</issn><issn>1879-2731</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKA0EQRRtRMEY_QeiFiC5G-zWPXokEXxAQNK6bTk0NaZmZHrsnQnb-g3_olzhJRJeuiqLOrcu9hBxzdsEZzy6fGVMsyZhmZ1qfM8akTtIdMuJFrhORS75LRr_IPjmI8XWAuBByRJ5mC9fSytVNpL6ina9XtnW1a_Hr43OzQVjVDqgFV1LwTeej65HOVxQW2DiwNZ3bfkFL3Fycbw_JXmXriEc_c0xebm9mk_tk-nj3MLmeJqCk7BNlYa4zZoVUXMhci7QsCglZiaKEvJAZA9S8ZClWVldZmqWFKoRkXOXzTPBcjsnp9m8X_NsSY28aFwHr2rbol9GInOcq1XIA0y0IwccYsDJdcI0NK8OZWTdoNg2adT1Ga7Np0KSD7uTHwMYhZxVsCy7-iTWTUqkBu9piOIR9dxhMBIctYOkCQm9K7_4x-gYJF4Vm</recordid><startdate>19990622</startdate><enddate>19990622</enddate><creator>Hu, Hailin</creator><creator>Saniger, José M.</creator><creator>Bañuelos, José G.</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>19990622</creationdate><title>Thin films of polyaniline–polyacrylic acid composite by chemical bath deposition</title><author>Hu, Hailin ; Saniger, José M. ; Bañuelos, José G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c433t-4acb960a2341237925d883c6de2dc78360ce91d05efa9f6565848230147b62173</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Applied sciences</topic><topic>Atomic force microscopy</topic><topic>Chemical bath deposition</topic><topic>Composite thin films</topic><topic>Exact sciences and technology</topic><topic>Fourier transform infrared spectrum</topic><topic>Optical absorption coefficient</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polyacrylic acid</topic><topic>Polyaniline</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Hailin</creatorcontrib><creatorcontrib>Saniger, José M.</creatorcontrib><creatorcontrib>Bañuelos, José G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Thin solid films</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Hailin</au><au>Saniger, José M.</au><au>Bañuelos, José G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thin films of polyaniline–polyacrylic acid composite by chemical bath deposition</atitle><jtitle>Thin solid films</jtitle><date>1999-06-22</date><risdate>1999</risdate><volume>347</volume><issue>1</issue><spage>241</spage><epage>247</epage><pages>241-247</pages><issn>0040-6090</issn><eissn>1879-2731</eissn><coden>THSFAP</coden><abstract>Polyaniline (PANI)–polyacrylic acid (PAA) composite thin films were deposited at room temperature on glass and polymethyl methacrylate substrates by introducing these into a freshly prepared chemical bath of HCl, PAA, aniline monomers and (NH
4)
2S
2O
8. Compared to the single PANI films, which were obtained from the same bath constitution but without PAA solution, the composite films showed a red shift at the maximum optical transmittance peak and a slightly lower electrical conductivity. Fourier transform infrared spectroscopy studies of the PANI composite thin films indicated the presence of the acid-base reaction product between PANI and PAA, as well as PAA molecule incorporation in the films. Atomic force microscopy analysis also showed morphologic and mechanical elasticity differences between the single PANI film the composite films deposited by the chemical bath method.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/S0040-6090(99)00039-5</doi><tpages>7</tpages></addata></record> |
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| ispartof | Thin solid films, 1999-06, Vol.347 (1), p.241-247 |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Atomic force microscopy Chemical bath deposition Composite thin films Exact sciences and technology Fourier transform infrared spectrum Optical absorption coefficient Organic polymers Physicochemistry of polymers Polyacrylic acid Polyaniline Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Thin films of polyaniline–polyacrylic acid composite by chemical bath deposition |
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