Expanding the series of alkali metal plumbolyl complexes to Na and K
Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis( tert -butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl TBS,Ph ). Their solid-state structures were found to comprise either monomeric solvates or coordination polymers depending on the...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2022-10, Vol.51 (38), p.1442-14428 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 14428 |
|---|---|
| container_issue | 38 |
| container_start_page | 1442 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 51 |
| creator | Diaz-Rodriguez, Roberto M Kitos, Alexandros A Murugesu, Muralee |
| description | Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis(
tert
-butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl
TBS,Ph
). Their solid-state structures were found to comprise either monomeric solvates or coordination polymers depending on the alkali metal ion and crystallization medium. These complexes were readily prepared with high yields and purity compared to known routes to the dilithium congener of Pbl
TBS,Ph
and are well-positioned to serve as convenient precursors for salt metathesis-type reactions leading to metal complexes of the understudied Pbl
TBS,Ph
ligand.
Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis(
tert
-butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl
TBS,Ph
). |
| doi_str_mv | 10.1039/d2dt02615e |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_proquest_miscellaneous_2716523452</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2720782184</sourcerecordid><originalsourceid>FETCH-LOGICAL-c244t-a75bb5a3fc9cece903cc79b63afa5ad9a5f2b4405639b0b0e0a0a8017c9e09ac3</originalsourceid><addsrcrecordid>eNpd0M9LwzAUB_AgCs7pxbsQ8CJC9SVp2uUobv7AoZd5Lq9pqp3pUpMWtv_e6GSCh_By-LzHe19CThlcMRDquuJVDzxj0uyREUvzPFFcpPu7P88OyVEISwDOQfIRmc7WHa6qZvVG-3dDg_GNCdTVFO0H2oa2pkdLOzu0pbMbS7VrO2vW0fSOPiONvfTpmBzUaIM5-a1j8no3W9w-JPOX-8fbm3mieZr2CeayLCWKWitttFEgtM5VmQmsUWKlUNa8TFOQmVAllGAAASfAcq0MKNRiTC62czvvPgcT-qJtgjbW4sq4IRQ8Z5mM98Y3Juf_6NINfhW3i4pDPuFskkZ1uVXauxC8qYvONy36TcGg-A60mPLp4ifQWcRnW-yD3rm_wMUXezdxZA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2720782184</pqid></control><display><type>article</type><title>Expanding the series of alkali metal plumbolyl complexes to Na and K</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Diaz-Rodriguez, Roberto M ; Kitos, Alexandros A ; Murugesu, Muralee</creator><creatorcontrib>Diaz-Rodriguez, Roberto M ; Kitos, Alexandros A ; Murugesu, Muralee</creatorcontrib><description>Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis(
tert
-butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl
TBS,Ph
). Their solid-state structures were found to comprise either monomeric solvates or coordination polymers depending on the alkali metal ion and crystallization medium. These complexes were readily prepared with high yields and purity compared to known routes to the dilithium congener of Pbl
TBS,Ph
and are well-positioned to serve as convenient precursors for salt metathesis-type reactions leading to metal complexes of the understudied Pbl
TBS,Ph
ligand.
Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis(
tert
-butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl
TBS,Ph
).</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d2dt02615e</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Anions ; Coordination compounds ; Coordination polymers ; Crystallization ; Metathesis ; Sodium</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2022-10, Vol.51 (38), p.1442-14428</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c244t-a75bb5a3fc9cece903cc79b63afa5ad9a5f2b4405639b0b0e0a0a8017c9e09ac3</citedby><cites>FETCH-LOGICAL-c244t-a75bb5a3fc9cece903cc79b63afa5ad9a5f2b4405639b0b0e0a0a8017c9e09ac3</cites><orcidid>0000-0002-4778-0687 ; 0000-0002-5123-374X ; 0000-0002-1431-3206</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Diaz-Rodriguez, Roberto M</creatorcontrib><creatorcontrib>Kitos, Alexandros A</creatorcontrib><creatorcontrib>Murugesu, Muralee</creatorcontrib><title>Expanding the series of alkali metal plumbolyl complexes to Na and K</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis(
tert
-butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl
TBS,Ph
). Their solid-state structures were found to comprise either monomeric solvates or coordination polymers depending on the alkali metal ion and crystallization medium. These complexes were readily prepared with high yields and purity compared to known routes to the dilithium congener of Pbl
TBS,Ph
and are well-positioned to serve as convenient precursors for salt metathesis-type reactions leading to metal complexes of the understudied Pbl
TBS,Ph
ligand.
Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis(
tert
-butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl
TBS,Ph
).</description><subject>Anions</subject><subject>Coordination compounds</subject><subject>Coordination polymers</subject><subject>Crystallization</subject><subject>Metathesis</subject><subject>Sodium</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpd0M9LwzAUB_AgCs7pxbsQ8CJC9SVp2uUobv7AoZd5Lq9pqp3pUpMWtv_e6GSCh_By-LzHe19CThlcMRDquuJVDzxj0uyREUvzPFFcpPu7P88OyVEISwDOQfIRmc7WHa6qZvVG-3dDg_GNCdTVFO0H2oa2pkdLOzu0pbMbS7VrO2vW0fSOPiONvfTpmBzUaIM5-a1j8no3W9w-JPOX-8fbm3mieZr2CeayLCWKWitttFEgtM5VmQmsUWKlUNa8TFOQmVAllGAAASfAcq0MKNRiTC62czvvPgcT-qJtgjbW4sq4IRQ8Z5mM98Y3Juf_6NINfhW3i4pDPuFskkZ1uVXauxC8qYvONy36TcGg-A60mPLp4ifQWcRnW-yD3rm_wMUXezdxZA</recordid><startdate>20221004</startdate><enddate>20221004</enddate><creator>Diaz-Rodriguez, Roberto M</creator><creator>Kitos, Alexandros A</creator><creator>Murugesu, Muralee</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4778-0687</orcidid><orcidid>https://orcid.org/0000-0002-5123-374X</orcidid><orcidid>https://orcid.org/0000-0002-1431-3206</orcidid></search><sort><creationdate>20221004</creationdate><title>Expanding the series of alkali metal plumbolyl complexes to Na and K</title><author>Diaz-Rodriguez, Roberto M ; Kitos, Alexandros A ; Murugesu, Muralee</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c244t-a75bb5a3fc9cece903cc79b63afa5ad9a5f2b4405639b0b0e0a0a8017c9e09ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anions</topic><topic>Coordination compounds</topic><topic>Coordination polymers</topic><topic>Crystallization</topic><topic>Metathesis</topic><topic>Sodium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Diaz-Rodriguez, Roberto M</creatorcontrib><creatorcontrib>Kitos, Alexandros A</creatorcontrib><creatorcontrib>Murugesu, Muralee</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Diaz-Rodriguez, Roberto M</au><au>Kitos, Alexandros A</au><au>Murugesu, Muralee</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Expanding the series of alkali metal plumbolyl complexes to Na and K</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2022-10-04</date><risdate>2022</risdate><volume>51</volume><issue>38</issue><spage>1442</spage><epage>14428</epage><pages>1442-14428</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis(
tert
-butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl
TBS,Ph
). Their solid-state structures were found to comprise either monomeric solvates or coordination polymers depending on the alkali metal ion and crystallization medium. These complexes were readily prepared with high yields and purity compared to known routes to the dilithium congener of Pbl
TBS,Ph
and are well-positioned to serve as convenient precursors for salt metathesis-type reactions leading to metal complexes of the understudied Pbl
TBS,Ph
ligand.
Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis(
tert
-butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl
TBS,Ph
).</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2dt02615e</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-4778-0687</orcidid><orcidid>https://orcid.org/0000-0002-5123-374X</orcidid><orcidid>https://orcid.org/0000-0002-1431-3206</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2022-10, Vol.51 (38), p.1442-14428 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2716523452 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anions Coordination compounds Coordination polymers Crystallization Metathesis Sodium |
| title | Expanding the series of alkali metal plumbolyl complexes to Na and K |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-17T13%3A15%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Expanding%20the%20series%20of%20alkali%20metal%20plumbolyl%20complexes%20to%20Na%20and%20K&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Diaz-Rodriguez,%20Roberto%20M&rft.date=2022-10-04&rft.volume=51&rft.issue=38&rft.spage=1442&rft.epage=14428&rft.pages=1442-14428&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/d2dt02615e&rft_dat=%3Cproquest_rsc_p%3E2720782184%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2720782184&rft_id=info:pmid/&rfr_iscdi=true |