Ru()-catalyzed external auxiliary-free primary amide-directed inverse Sonogashira reaction on (hetero)arylamides

Herein, we report ruthenium( ii )-catalyzed weakly coordinating primary amide-assisted ortho -di-alkynylation of (hetero)arylamides via double C-H bond activation in the presence of bromo-alkynes as coupling partners. The attractive features of the developed strategy lie in the usage of an inexpensi...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2022-10, Vol.58 (8), p.1134-1137
Hauptverfasser:	Baghel, Akanksha Singh, Kumar, Amit
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Chemical synthesis Hydrogen bonds Ruthenium Ruthenium compounds Substrates
Online-Zugang:	Volltext
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