Coordination chemistry and structural rearrangements of the Me2PCH2AlMe2 ambiphilic ligand

Reaction of 2 equivalents of (Me2PCH2AlMe2)2 with [{RhCl(cod)}2] (cod = 1,5-cyclooctadiene) afforded [{κ2P,P-(Me3Al)ClMeAl(CH2PMe2)2}Rh(cod)] (1), which features a κ2-coordinated bis(phosphino)aluminate anion. In compound 1, an Al–Cl substituent bridges to a molecule of AlMe3, which could be removed...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-10, Vol.51 (39), p.15040-15048
Hauptverfasser:	Paskaruk, Katarina, Emslie, David J H, Britten, James F
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Anions Benzene Chlorides Chlorine compounds Crystallography Equivalence Ethane Gold Iridium Ligands Phosphines Rhodium Toluene Transition metals
Online-Zugang:	Volltext
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