Grain-dependent passivation of surfaces of polycrystalline zinc
Effects of texture on the electrochemical behaviors of single grains in polycrystalline zinc were investigated using a capillary-based micro-droplet cell. Pontiodynamic sweeps and capacity measurements were carried out in pH 9 borate buffer solution. The cyclic voltammograms and the capacity measure...
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| Veröffentlicht in: | Electrochimica acta 2002-08, Vol.47 (21), p.3395-3399 |
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| container_issue | 21 |
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| container_title | Electrochimica acta |
| container_volume | 47 |
| creator | Park, C.J. Lohrengel, M.M. Hamelmann, T. Pilaski, M. Kwon, H.S. |
| description | Effects of texture on the electrochemical behaviors of single grains in polycrystalline zinc were investigated using a capillary-based micro-droplet cell. Pontiodynamic sweeps and capacity measurements were carried out in pH 9 borate buffer solution. The cyclic voltammograms and the capacity measurements on single grains with different crystallographic orientations in polycrystalline Zn showed a strong dependence of oxide growth on crystallographic grain orientation. The total charge consumed for oxide formation and the inverse capacity increased with an increase of surface packing density of grain, suggesting the oxide formation was greater on grains with higher surface packing density. |
| doi_str_mv | 10.1016/S0013-4686(02)00221-9 |
| format | Article |
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Pontiodynamic sweeps and capacity measurements were carried out in pH 9 borate buffer solution. The cyclic voltammograms and the capacity measurements on single grains with different crystallographic orientations in polycrystalline Zn showed a strong dependence of oxide growth on crystallographic grain orientation. The total charge consumed for oxide formation and the inverse capacity increased with an increase of surface packing density of grain, suggesting the oxide formation was greater on grains with higher surface packing density.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/S0013-4686(02)00221-9</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Capacity ; Corrosion ; Corrosion mechanisms ; Cyclic voltammogram ; Exact sciences and technology ; Metals. 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Pontiodynamic sweeps and capacity measurements were carried out in pH 9 borate buffer solution. The cyclic voltammograms and the capacity measurements on single grains with different crystallographic orientations in polycrystalline Zn showed a strong dependence of oxide growth on crystallographic grain orientation. The total charge consumed for oxide formation and the inverse capacity increased with an increase of surface packing density of grain, suggesting the oxide formation was greater on grains with higher surface packing density.</description><subject>Applied sciences</subject><subject>Capacity</subject><subject>Corrosion</subject><subject>Corrosion mechanisms</subject><subject>Cyclic voltammogram</subject><subject>Exact sciences and technology</subject><subject>Metals. Metallurgy</subject><subject>Micro-droplet cell</subject><subject>Oxide growth</subject><subject>Texture</subject><subject>Zinc</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKs_QehF0cPqZLPJ7p6KFK1CwYN6DtNkApFtdk22hfrr7Rd69DRzeN55mYexSw53HLi6fwPgIitUpW4gvwXIc57VR2zAq1JkopL1MRv8IqfsLKVPAChVCQM2nkb0IbPUUbAU-lGHKfkV9r4No9aN0jI6NJS2e9c2axPXqcem8YFG3z6Yc3bisEl0cZhD9vH0-D55zmav05fJwywzQlV95rA0LpfW1txZpEKYWtZzwlqhQ4tSkKwKQFcppSwaWSKBKHCey5LA5nMxZNf7u11sv5aUer3wyVDTYKB2mXRe8qIohdiAcg-a2KYUyeku-gXGteagt7r0TpfeutCQ650uXW9yV4cCTAYbFzEYn_7Coiokr2DDjfccbb5deYo6GU_BkPWRTK9t6_9p-gFos4BS</recordid><startdate>20020815</startdate><enddate>20020815</enddate><creator>Park, C.J.</creator><creator>Lohrengel, M.M.</creator><creator>Hamelmann, T.</creator><creator>Pilaski, M.</creator><creator>Kwon, H.S.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20020815</creationdate><title>Grain-dependent passivation of surfaces of polycrystalline zinc</title><author>Park, C.J. ; Lohrengel, M.M. ; Hamelmann, T. ; Pilaski, M. ; Kwon, H.S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-fa7cf25dd91fdae43c959bea96afada53e5840af8666dac57ae034ab257e0d2b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Applied sciences</topic><topic>Capacity</topic><topic>Corrosion</topic><topic>Corrosion mechanisms</topic><topic>Cyclic voltammogram</topic><topic>Exact sciences and technology</topic><topic>Metals. Metallurgy</topic><topic>Micro-droplet cell</topic><topic>Oxide growth</topic><topic>Texture</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Park, C.J.</creatorcontrib><creatorcontrib>Lohrengel, M.M.</creatorcontrib><creatorcontrib>Hamelmann, T.</creatorcontrib><creatorcontrib>Pilaski, M.</creatorcontrib><creatorcontrib>Kwon, H.S.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Park, C.J.</au><au>Lohrengel, M.M.</au><au>Hamelmann, T.</au><au>Pilaski, M.</au><au>Kwon, H.S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Grain-dependent passivation of surfaces of polycrystalline zinc</atitle><jtitle>Electrochimica acta</jtitle><date>2002-08-15</date><risdate>2002</risdate><volume>47</volume><issue>21</issue><spage>3395</spage><epage>3399</epage><pages>3395-3399</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>Effects of texture on the electrochemical behaviors of single grains in polycrystalline zinc were investigated using a capillary-based micro-droplet cell. Pontiodynamic sweeps and capacity measurements were carried out in pH 9 borate buffer solution. The cyclic voltammograms and the capacity measurements on single grains with different crystallographic orientations in polycrystalline Zn showed a strong dependence of oxide growth on crystallographic grain orientation. The total charge consumed for oxide formation and the inverse capacity increased with an increase of surface packing density of grain, suggesting the oxide formation was greater on grains with higher surface packing density.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0013-4686(02)00221-9</doi><tpages>5</tpages></addata></record> |
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| ispartof | Electrochimica acta, 2002-08, Vol.47 (21), p.3395-3399 |
| issn | 0013-4686 1873-3859 |
| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Applied sciences Capacity Corrosion Corrosion mechanisms Cyclic voltammogram Exact sciences and technology Metals. Metallurgy Micro-droplet cell Oxide growth Texture Zinc |
| title | Grain-dependent passivation of surfaces of polycrystalline zinc |
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