Sensing performance and mechanism of carbon dots encapsulated into metal–organic frameworks

Metal–organic frameworks (MOFs) can be combined with nanomaterials and the combined composites have excellent optical properties. Carbon dots (CDs) with tiny particle size, non-toxic and rich surface functional groups are novel fluorescent materials. Carbon dots@metal–organic frameworks (CDs@MOFs) a...

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Veröffentlicht in:Mikrochimica acta (1966) 2022-10, Vol.189 (10), p.379-379, Article 379
Hauptverfasser: Yan, Fanyong, Wang, Xiule, Wang, Yao, Yi, Chunhui, Xu, Ming, Xu, Jinxia
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container_end_page 379
container_issue 10
container_start_page 379
container_title Mikrochimica acta (1966)
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creator Yan, Fanyong
Wang, Xiule
Wang, Yao
Yi, Chunhui
Xu, Ming
Xu, Jinxia
description Metal–organic frameworks (MOFs) can be combined with nanomaterials and the combined composites have excellent optical properties. Carbon dots (CDs) with tiny particle size, non-toxic and rich surface functional groups are novel fluorescent materials. Carbon dots@metal–organic frameworks (CDs@MOFs) are synthesized by encapsulating CDs into MOFs. CDs@MOFs are promising composites for the preparation of a new generation of fluorescence sensors, which combine the hybrid properties of MOFs and the special optical properties of CDs. Urged as such, we are encouraged to categorize according to the sensing mechanisms. These include fluorescence resonance energy transfer (FRET), aggregation-caused quenching (ACQ), static quenching, dynamic quenching, photo-induced electron transfer (PET), inner filter effect (IFE) and so on. Based on the above mechanisms, CDs@MOFs can specifically interact with target analytes to generate fluorescence quenching. This review covers the research progress of CDs@MOFs in recent five years (with 103 refs), synthetic design of CDs@MOFs and introduces the sensing mechanism. The current challenges and future research directions are discussed briefly. Graphical abstract The sensing mechanism and applications of CDs@MOFs
doi_str_mv 10.1007/s00604-022-05481-5
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Carbon dots (CDs) with tiny particle size, non-toxic and rich surface functional groups are novel fluorescent materials. Carbon dots@metal–organic frameworks (CDs@MOFs) are synthesized by encapsulating CDs into MOFs. CDs@MOFs are promising composites for the preparation of a new generation of fluorescence sensors, which combine the hybrid properties of MOFs and the special optical properties of CDs. Urged as such, we are encouraged to categorize according to the sensing mechanisms. These include fluorescence resonance energy transfer (FRET), aggregation-caused quenching (ACQ), static quenching, dynamic quenching, photo-induced electron transfer (PET), inner filter effect (IFE) and so on. Based on the above mechanisms, CDs@MOFs can specifically interact with target analytes to generate fluorescence quenching. This review covers the research progress of CDs@MOFs in recent five years (with 103 refs), synthetic design of CDs@MOFs and introduces the sensing mechanism. 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subjects Analytical Chemistry
Carbon
Carbon dots
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Composite materials
Electron transfer
Encapsulation
Energy transfer
Fluorescence
Functional groups
Metal-organic frameworks
Microengineering
Nanochemistry
Nanomaterials
Nanotechnology
Optical properties
Quenching
Review Article
Sensors
title Sensing performance and mechanism of carbon dots encapsulated into metal–organic frameworks
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