Cathode properties of pyrophosphates for rechargeable lithium batteries
Two rechargeable pyrophosphates, LiVP 2O 7 and TiP 2O 7, were synthesized by a solid state reaction, and the cathode properties were investigated. The structures were characterized by powder X-ray Rietveld refinement. LiVP 2O 7 was isostructural with P2 1 monoclinic LiFeP 2O 7 and TiP 2O 7 was isost...
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| Veröffentlicht in: | Solid state ionics 2002-06, Vol.148 (3), p.323-328 |
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| container_end_page | 328 |
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| container_title | Solid state ionics |
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| creator | Uebou, Yasushi Okada, Shigeto Egashira, Minato Yamaki, Jun-Ichi |
| description | Two rechargeable pyrophosphates, LiVP
2O
7 and TiP
2O
7, were synthesized by a solid state reaction, and the cathode properties were investigated. The structures were characterized by powder X-ray Rietveld refinement. LiVP
2O
7 was isostructural with
P2
1 monoclinic LiFeP
2O
7 and TiP
2O
7 was isostructural with
Pa3 cubic ZrV
2O
7. Lithium cells using LiVP
2O
7 cathodes showed that approximately 0.5 Li per unit could be reversibly deintercalated from LiVP
2O
7 at 4.1 V vs. Li/Li
+. On the other hand, 0.6 Li per unit could be reversibly intercalated into TiP
2O
7 at 2.6 V vs. Li/Li
+. |
| doi_str_mv | 10.1016/S0167-2738(02)00069-3 |
| format | Article |
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2O
7 and TiP
2O
7, were synthesized by a solid state reaction, and the cathode properties were investigated. The structures were characterized by powder X-ray Rietveld refinement. LiVP
2O
7 was isostructural with
P2
1 monoclinic LiFeP
2O
7 and TiP
2O
7 was isostructural with
Pa3 cubic ZrV
2O
7. Lithium cells using LiVP
2O
7 cathodes showed that approximately 0.5 Li per unit could be reversibly deintercalated from LiVP
2O
7 at 4.1 V vs. Li/Li
+. On the other hand, 0.6 Li per unit could be reversibly intercalated into TiP
2O
7 at 2.6 V vs. Li/Li
+.</description><identifier>ISSN: 0167-2738</identifier><identifier>EISSN: 1872-7689</identifier><identifier>DOI: 10.1016/S0167-2738(02)00069-3</identifier><identifier>CODEN: SSIOD3</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Cathode-active materials ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Exact sciences and technology ; Lithium secondary batteries ; Pyrophosphates</subject><ispartof>Solid state ionics, 2002-06, Vol.148 (3), p.323-328</ispartof><rights>2002 Elsevier Science B.V.</rights><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c434t-13531df45b49244fef1694f04489f56e7207aa1c151f219d27305aea31f7ba8c3</citedby><cites>FETCH-LOGICAL-c434t-13531df45b49244fef1694f04489f56e7207aa1c151f219d27305aea31f7ba8c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0167-2738(02)00069-3$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,3549,23929,23930,25139,27923,27924,45994</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13688756$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Uebou, Yasushi</creatorcontrib><creatorcontrib>Okada, Shigeto</creatorcontrib><creatorcontrib>Egashira, Minato</creatorcontrib><creatorcontrib>Yamaki, Jun-Ichi</creatorcontrib><title>Cathode properties of pyrophosphates for rechargeable lithium batteries</title><title>Solid state ionics</title><description>Two rechargeable pyrophosphates, LiVP
2O
7 and TiP
2O
7, were synthesized by a solid state reaction, and the cathode properties were investigated. The structures were characterized by powder X-ray Rietveld refinement. LiVP
2O
7 was isostructural with
P2
1 monoclinic LiFeP
2O
7 and TiP
2O
7 was isostructural with
Pa3 cubic ZrV
2O
7. Lithium cells using LiVP
2O
7 cathodes showed that approximately 0.5 Li per unit could be reversibly deintercalated from LiVP
2O
7 at 4.1 V vs. Li/Li
+. On the other hand, 0.6 Li per unit could be reversibly intercalated into TiP
2O
7 at 2.6 V vs. Li/Li
+.</description><subject>Applied sciences</subject><subject>Cathode-active materials</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Exact sciences and technology</subject><subject>Lithium secondary batteries</subject><subject>Pyrophosphates</subject><issn>0167-2738</issn><issn>1872-7689</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKs_QdiLoofVfO0mexIpWoWCB_Uc0uzEjWybNUmF_nvTD_ToJSHD82ZmHoTOCb4hmNS3r_kQJRVMXmF6jTGum5IdoBGRgpails0hGv0ix-gkxs8NxGQ9QtOJTp1voRiCHyAkB7HwthjW-dn5OHQ65Yr1oQhgOh0-QM97KHqXOrdaFHOdEoQcOkVHVvcRzvb3GL0_PrxNnsrZy_R5cj8rDWc8lYRVjLSWV3PeUM4tWFI33GLOZWOrGgTFQmtiSEUsJU2bJ8aVBs2IFXMtDRujy92_ed6vFcSkFi4a6Hu9BL-KigpC8248g9UONMHHGMCqIbiFDmtFsNpoU1ttauNEYaq22hTLuYt9Ax2N7m3QS-PiX5jVUoqqztzdjoO87beDoKJxsDTQumwqqda7fzr9AJcEgZ4</recordid><startdate>20020601</startdate><enddate>20020601</enddate><creator>Uebou, Yasushi</creator><creator>Okada, Shigeto</creator><creator>Egashira, Minato</creator><creator>Yamaki, Jun-Ichi</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20020601</creationdate><title>Cathode properties of pyrophosphates for rechargeable lithium batteries</title><author>Uebou, Yasushi ; Okada, Shigeto ; Egashira, Minato ; Yamaki, Jun-Ichi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c434t-13531df45b49244fef1694f04489f56e7207aa1c151f219d27305aea31f7ba8c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Applied sciences</topic><topic>Cathode-active materials</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Exact sciences and technology</topic><topic>Lithium secondary batteries</topic><topic>Pyrophosphates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Uebou, Yasushi</creatorcontrib><creatorcontrib>Okada, Shigeto</creatorcontrib><creatorcontrib>Egashira, Minato</creatorcontrib><creatorcontrib>Yamaki, Jun-Ichi</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Uebou, Yasushi</au><au>Okada, Shigeto</au><au>Egashira, Minato</au><au>Yamaki, Jun-Ichi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cathode properties of pyrophosphates for rechargeable lithium batteries</atitle><jtitle>Solid state ionics</jtitle><date>2002-06-01</date><risdate>2002</risdate><volume>148</volume><issue>3</issue><spage>323</spage><epage>328</epage><pages>323-328</pages><issn>0167-2738</issn><eissn>1872-7689</eissn><coden>SSIOD3</coden><abstract>Two rechargeable pyrophosphates, LiVP
2O
7 and TiP
2O
7, were synthesized by a solid state reaction, and the cathode properties were investigated. The structures were characterized by powder X-ray Rietveld refinement. LiVP
2O
7 was isostructural with
P2
1 monoclinic LiFeP
2O
7 and TiP
2O
7 was isostructural with
Pa3 cubic ZrV
2O
7. Lithium cells using LiVP
2O
7 cathodes showed that approximately 0.5 Li per unit could be reversibly deintercalated from LiVP
2O
7 at 4.1 V vs. Li/Li
+. On the other hand, 0.6 Li per unit could be reversibly intercalated into TiP
2O
7 at 2.6 V vs. Li/Li
+.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/S0167-2738(02)00069-3</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0167-2738 |
| ispartof | Solid state ionics, 2002-06, Vol.148 (3), p.323-328 |
| issn | 0167-2738 1872-7689 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | Applied sciences Cathode-active materials Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology Lithium secondary batteries Pyrophosphates |
| title | Cathode properties of pyrophosphates for rechargeable lithium batteries |
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