Preparation of polylactic acid composites containing β–Ca(PO3)2 fibers
Novel biomaterials for application to artificial bone with modulus of elasticity close to that of natural bone were prepared using bioresorbable poly-L-lactic acid (PLLA) and high-strength β–Ca(PO3)2 fibers treated with dilute NaOH solution. PLLA dissolved by using methylene chloride was mixed with...
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Veröffentlicht in: | Journal of materials research 1999-02, Vol.14 (2), p.418-424 |
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creator | Kasuga, Toshihiro Fujikawa, Haruhiko Abe, Yoshihiro |
description | Novel biomaterials for application to artificial bone with modulus of elasticity close to that of natural bone were prepared using bioresorbable poly-L-lactic acid (PLLA) and high-strength β–Ca(PO3)2 fibers treated with dilute NaOH solution. PLLA dissolved by using methylene chloride was mixed with the fibers. After drying the mixture, it was hot-pressed uniaxially under a pressure of 40 MPa at 180 °C, resulting in fabrication of a PLLA composite containing β–Ca(PO3)2 fibers. Almost no degradation in the bending strength was observed even when a large amount of the fibers (≈50 wt. %) was introduced, and the modulus of elasticity was increased effectively with increasing the fiber content. The PLLA composite with modulus of elasticity of |
doi_str_mv | 10.1557/JMR.1999.0060 |
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PLLA dissolved by using methylene chloride was mixed with the fibers. After drying the mixture, it was hot-pressed uniaxially under a pressure of 40 MPa at 180 °C, resulting in fabrication of a PLLA composite containing β–Ca(PO3)2 fibers. Almost no degradation in the bending strength was observed even when a large amount of the fibers (≈50 wt. %) was introduced, and the modulus of elasticity was increased effectively with increasing the fiber content. The PLLA composite with modulus of elasticity of <5 GPa similar to that of natural bone was found to be prepared when the fiber content was over 35 wt. %. The bending test of the composites showed that very high energy is consumed for their fracture and that the fracture proceeds step by step, even beyond the maximum stress.</description><identifier>ISSN: 0884-2914</identifier><identifier>EISSN: 2044-5326</identifier><identifier>DOI: 10.1557/JMR.1999.0060</identifier><language>eng</language><publisher>New York, USA: Cambridge University Press</publisher><ispartof>Journal of materials research, 1999-02, Vol.14 (2), p.418-424</ispartof><rights>Copyright © Materials Research Society 1999</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c259t-616eca58d24ed720ced63767382220f1fcce98513fe4982db48bd4bcc073c8163</citedby><cites>FETCH-LOGICAL-c259t-616eca58d24ed720ced63767382220f1fcce98513fe4982db48bd4bcc073c8163</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><contributor>WCA</contributor><creatorcontrib>Kasuga, Toshihiro</creatorcontrib><creatorcontrib>Fujikawa, Haruhiko</creatorcontrib><creatorcontrib>Abe, Yoshihiro</creatorcontrib><title>Preparation of polylactic acid composites containing β–Ca(PO3)2 fibers</title><title>Journal of materials research</title><addtitle>J. Mater. Res</addtitle><description>Novel biomaterials for application to artificial bone with modulus of elasticity close to that of natural bone were prepared using bioresorbable poly-L-lactic acid (PLLA) and high-strength β–Ca(PO3)2 fibers treated with dilute NaOH solution. PLLA dissolved by using methylene chloride was mixed with the fibers. After drying the mixture, it was hot-pressed uniaxially under a pressure of 40 MPa at 180 °C, resulting in fabrication of a PLLA composite containing β–Ca(PO3)2 fibers. Almost no degradation in the bending strength was observed even when a large amount of the fibers (≈50 wt. %) was introduced, and the modulus of elasticity was increased effectively with increasing the fiber content. The PLLA composite with modulus of elasticity of <5 GPa similar to that of natural bone was found to be prepared when the fiber content was over 35 wt. %. The bending test of the composites showed that very high energy is consumed for their fracture and that the fracture proceeds step by step, even beyond the maximum stress.</description><issn>0884-2914</issn><issn>2044-5326</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNp1kL1OwzAURi0EEqUwsmdCMKT1X2xnRBWUoqLSFmbLcZzKJY2DnUp04x14Ex6Eh-BJSNUKJqZ7h6Pvu_cAcI5gDyUJ798_zHooTdMehAwegA6GlMYJwewQdKAQNMYposfgJIQlhCiBnHbA6NGbWnnVWFdFrohqV25KpRurI6VtHmm3ql2wjQntWjXKVrZaRF-f3-8fA3X5OCFXOCpsZnw4BUeFKoM5288ueL69eRrcxePJcDS4HscaJ2kTM8SMVonIMTU5x1CbnBHOOBEYY1igQmuTigSRwtBU4DyjIstppjXkRAvESBdc7HJr717XJjRyZYM2Zakq49ZBYo4gR21AF8Q7UHsXgjeFrL1dKb-RCMqtMNkKk1thcivsj7ehMW-_sPIvsj2PJ5INp3LM5mgm5lNJWr6_z1erzNt8YeTSrX3VPv9Pww8t130H</recordid><startdate>199902</startdate><enddate>199902</enddate><creator>Kasuga, Toshihiro</creator><creator>Fujikawa, Haruhiko</creator><creator>Abe, Yoshihiro</creator><general>Cambridge University Press</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>199902</creationdate><title>Preparation of polylactic acid composites containing β–Ca(PO3)2 fibers</title><author>Kasuga, Toshihiro ; Fujikawa, Haruhiko ; Abe, Yoshihiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c259t-616eca58d24ed720ced63767382220f1fcce98513fe4982db48bd4bcc073c8163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kasuga, Toshihiro</creatorcontrib><creatorcontrib>Fujikawa, Haruhiko</creatorcontrib><creatorcontrib>Abe, Yoshihiro</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of materials research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kasuga, Toshihiro</au><au>Fujikawa, Haruhiko</au><au>Abe, Yoshihiro</au><au>WCA</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of polylactic acid composites containing β–Ca(PO3)2 fibers</atitle><jtitle>Journal of materials research</jtitle><addtitle>J. Mater. Res</addtitle><date>1999-02</date><risdate>1999</risdate><volume>14</volume><issue>2</issue><spage>418</spage><epage>424</epage><pages>418-424</pages><issn>0884-2914</issn><eissn>2044-5326</eissn><abstract>Novel biomaterials for application to artificial bone with modulus of elasticity close to that of natural bone were prepared using bioresorbable poly-L-lactic acid (PLLA) and high-strength β–Ca(PO3)2 fibers treated with dilute NaOH solution. PLLA dissolved by using methylene chloride was mixed with the fibers. After drying the mixture, it was hot-pressed uniaxially under a pressure of 40 MPa at 180 °C, resulting in fabrication of a PLLA composite containing β–Ca(PO3)2 fibers. Almost no degradation in the bending strength was observed even when a large amount of the fibers (≈50 wt. %) was introduced, and the modulus of elasticity was increased effectively with increasing the fiber content. The PLLA composite with modulus of elasticity of <5 GPa similar to that of natural bone was found to be prepared when the fiber content was over 35 wt. %. The bending test of the composites showed that very high energy is consumed for their fracture and that the fracture proceeds step by step, even beyond the maximum stress.</abstract><cop>New York, USA</cop><pub>Cambridge University Press</pub><doi>10.1557/JMR.1999.0060</doi><tpages>7</tpages></addata></record> |
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title | Preparation of polylactic acid composites containing β–Ca(PO3)2 fibers |
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