Visible light assisted surface plasmon resonance triggered Ag/ZnO nanocomposites: synthesis and performance towards degradation of indigo carmine dye
Water pollution caused by organic compounds, generated from different industries, has gained attention worldwide today. In this regard, significant efforts have been made for a suitable dye degradation technology. Zinc oxide (ZnO)–based photocatalysts are considered novel materials to degrade orga...
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| Veröffentlicht in: | Environmental science and pollution research international 2023-09, Vol.30 (44), p.98619-98631 |
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| creator | Kumar, Rahul Janbandhu, Shaileshkumar Y. Sukhadeve, Gaurav K. Gedam, Rupesh S. |
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Water pollution caused by organic compounds, generated from different industries, has gained attention worldwide today. In this regard, significant efforts have been made for a suitable dye degradation technology. Zinc oxide (ZnO)–based photocatalysts are considered novel materials to degrade organic effluents in contaminated water. The facile synthesis of Ag/ZnO nanocomposites and its application for the enhanced degradation of indigo carmine (IC) dye under visible light irradiation is reported in this paper. The prepared photocatalysts were characterized using various analytical techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron (XPS) spectroscopy, FTIR, Raman, impedance study, UV–Vis, and photoluminescence (PL). Prepared Ag/ZnO nanocomposites were tested for degradation of IC dye in visible light. The degradation efficiency of IC dye was found to be 95.71% in 120 min, with a rate constant of 0.02021 min
−1
. This improved photocatalytic activity of Ag/ZnO nanocomposites was mainly due to the absorption of visible light caused by surface plasmon resonance (SPR) derived from Ag nanoparticles (NPs) and electron–hole separation. Radical trapping experiments suggest that holes (h
+
) and superoxide radical (O
2
•
–
) are the key factors in photocatalytic IC dye degradation. |
| doi_str_mv | 10.1007/s11356-022-22745-y |
| format | Article |
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Water pollution caused by organic compounds, generated from different industries, has gained attention worldwide today. In this regard, significant efforts have been made for a suitable dye degradation technology. Zinc oxide (ZnO)–based photocatalysts are considered novel materials to degrade organic effluents in contaminated water. The facile synthesis of Ag/ZnO nanocomposites and its application for the enhanced degradation of indigo carmine (IC) dye under visible light irradiation is reported in this paper. The prepared photocatalysts were characterized using various analytical techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron (XPS) spectroscopy, FTIR, Raman, impedance study, UV–Vis, and photoluminescence (PL). Prepared Ag/ZnO nanocomposites were tested for degradation of IC dye in visible light. The degradation efficiency of IC dye was found to be 95.71% in 120 min, with a rate constant of 0.02021 min
−1
. This improved photocatalytic activity of Ag/ZnO nanocomposites was mainly due to the absorption of visible light caused by surface plasmon resonance (SPR) derived from Ag nanoparticles (NPs) and electron–hole separation. Radical trapping experiments suggest that holes (h
+
) and superoxide radical (O
2
•
–
) are the key factors in photocatalytic IC dye degradation.</description><identifier>ISSN: 1614-7499</identifier><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-022-22745-y</identifier><identifier>PMID: 36053425</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Advanced Materials for Energy & Applications ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Carmine ; Catalysis ; Catalytic activity ; Degradation ; Dyes ; Earth and Environmental Science ; Ecotoxicology ; Electrons ; Environment ; Environmental Chemistry ; Environmental Health ; High resolution electron microscopy ; Indigo ; Indigo Carmine ; Irradiation ; Light ; Light irradiation ; Metal Nanoparticles - chemistry ; Microscopy ; Nanocomposites ; Nanocomposites - chemistry ; Nanoparticles ; Organic compounds ; Performance degradation ; Photocatalysis ; Photocatalysts ; Photodegradation ; Photoelectrons ; Photoluminescence ; Photons ; Resonance ; Scanning electron microscopy ; Silver ; Silver - chemistry ; Surface Plasmon Resonance ; Synthesis ; Transmission electron microscopy ; Waste Water Technology ; Water Management ; Water pollution ; Water Pollution Control ; X ray photoelectron spectroscopy ; X-ray diffraction ; Zinc oxide ; Zinc Oxide - chemistry ; Zinc oxides</subject><ispartof>Environmental science and pollution research international, 2023-09, Vol.30 (44), p.98619-98631</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-e6fda5642b79ce2ea8bbe8591677f70cd53415b9dd09896f2e5dbbc8cc9ef6cb3</citedby><cites>FETCH-LOGICAL-c419t-e6fda5642b79ce2ea8bbe8591677f70cd53415b9dd09896f2e5dbbc8cc9ef6cb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-022-22745-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-022-22745-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36053425$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kumar, Rahul</creatorcontrib><creatorcontrib>Janbandhu, Shaileshkumar Y.</creatorcontrib><creatorcontrib>Sukhadeve, Gaurav K.</creatorcontrib><creatorcontrib>Gedam, Rupesh S.</creatorcontrib><title>Visible light assisted surface plasmon resonance triggered Ag/ZnO nanocomposites: synthesis and performance towards degradation of indigo carmine dye</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>
Water pollution caused by organic compounds, generated from different industries, has gained attention worldwide today. In this regard, significant efforts have been made for a suitable dye degradation technology. Zinc oxide (ZnO)–based photocatalysts are considered novel materials to degrade organic effluents in contaminated water. The facile synthesis of Ag/ZnO nanocomposites and its application for the enhanced degradation of indigo carmine (IC) dye under visible light irradiation is reported in this paper. The prepared photocatalysts were characterized using various analytical techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron (XPS) spectroscopy, FTIR, Raman, impedance study, UV–Vis, and photoluminescence (PL). Prepared Ag/ZnO nanocomposites were tested for degradation of IC dye in visible light. The degradation efficiency of IC dye was found to be 95.71% in 120 min, with a rate constant of 0.02021 min
−1
. This improved photocatalytic activity of Ag/ZnO nanocomposites was mainly due to the absorption of visible light caused by surface plasmon resonance (SPR) derived from Ag nanoparticles (NPs) and electron–hole separation. Radical trapping experiments suggest that holes (h
+
) and superoxide radical (O
2
•
–
) are the key factors in photocatalytic IC dye degradation.</description><subject>Advanced Materials for Energy & Applications</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Carmine</subject><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Degradation</subject><subject>Dyes</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Electrons</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>High resolution electron microscopy</subject><subject>Indigo</subject><subject>Indigo Carmine</subject><subject>Irradiation</subject><subject>Light</subject><subject>Light irradiation</subject><subject>Metal Nanoparticles - chemistry</subject><subject>Microscopy</subject><subject>Nanocomposites</subject><subject>Nanocomposites - chemistry</subject><subject>Nanoparticles</subject><subject>Organic compounds</subject><subject>Performance degradation</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Photodegradation</subject><subject>Photoelectrons</subject><subject>Photoluminescence</subject><subject>Photons</subject><subject>Resonance</subject><subject>Scanning electron microscopy</subject><subject>Silver</subject><subject>Silver - chemistry</subject><subject>Surface Plasmon Resonance</subject><subject>Synthesis</subject><subject>Transmission electron microscopy</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water pollution</subject><subject>Water Pollution Control</subject><subject>X ray photoelectron spectroscopy</subject><subject>X-ray diffraction</subject><subject>Zinc oxide</subject><subject>Zinc Oxide - chemistry</subject><subject>Zinc oxides</subject><issn>1614-7499</issn><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kctu0DAQRSMEoqXwAyyQJTZsQm0nsWN2VcVLqtQNsGBj-TFJXSV28CRC-RD-F0PKQyxY2Rqfe8czt6qeMvqSUSrPkbGmEzXlvOZctl2936tOmWBtLVul7v91P6keId5Syqni8mF10gjaNS3vTqtvnwIGOwGZwnizEoMYcAVPcMuDcUCWyeCcIsmAKZpYKmsO4wi5MBfj-ed4TUo5uTQvCcMK-IrgHtcbKD7ERE8WyEPK8yFNX032SDyM2XizhmKcBhKiD2MizuQ5RCB-h8fVg8FMCE_uzrPq45vXHy7f1VfXb99fXlzVrmVqrUEM3nSi5VYqBxxMby30nWJCykFS58uQrLPKe6p6JQYOnbfW9c4pGISzzVn14vBdcvqyAa56DuhgmkyEtKHmkirZciVVQZ__g96mLcfyO817oRrFW8kKxQ_K5YSYYdBLDrPJu2ZU_whNH6HpEpr-GZrei-jZnfVmZ_C_Jb9SKkBzAFieYln-n97_sf0O0xKnJw</recordid><startdate>20230901</startdate><enddate>20230901</enddate><creator>Kumar, Rahul</creator><creator>Janbandhu, Shaileshkumar Y.</creator><creator>Sukhadeve, Gaurav K.</creator><creator>Gedam, Rupesh S.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7X8</scope></search><sort><creationdate>20230901</creationdate><title>Visible light assisted surface plasmon resonance triggered Ag/ZnO nanocomposites: synthesis and performance towards degradation of indigo carmine dye</title><author>Kumar, Rahul ; Janbandhu, Shaileshkumar Y. ; Sukhadeve, Gaurav K. ; Gedam, Rupesh S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-e6fda5642b79ce2ea8bbe8591677f70cd53415b9dd09896f2e5dbbc8cc9ef6cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Advanced Materials for Energy & Applications</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Carmine</topic><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Degradation</topic><topic>Dyes</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Electrons</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>High resolution electron microscopy</topic><topic>Indigo</topic><topic>Indigo Carmine</topic><topic>Irradiation</topic><topic>Light</topic><topic>Light irradiation</topic><topic>Metal Nanoparticles - chemistry</topic><topic>Microscopy</topic><topic>Nanocomposites</topic><topic>Nanocomposites - chemistry</topic><topic>Nanoparticles</topic><topic>Organic compounds</topic><topic>Performance degradation</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Photodegradation</topic><topic>Photoelectrons</topic><topic>Photoluminescence</topic><topic>Photons</topic><topic>Resonance</topic><topic>Scanning electron microscopy</topic><topic>Silver</topic><topic>Silver - chemistry</topic><topic>Surface Plasmon Resonance</topic><topic>Synthesis</topic><topic>Transmission electron microscopy</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water pollution</topic><topic>Water Pollution Control</topic><topic>X ray photoelectron spectroscopy</topic><topic>X-ray diffraction</topic><topic>Zinc oxide</topic><topic>Zinc Oxide - chemistry</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kumar, Rahul</creatorcontrib><creatorcontrib>Janbandhu, Shaileshkumar Y.</creatorcontrib><creatorcontrib>Sukhadeve, Gaurav K.</creatorcontrib><creatorcontrib>Gedam, Rupesh S.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Access via ABI/INFORM (ProQuest)</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Public Health Database</collection><collection>Technology Research Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Business Premium Collection (Alumni)</collection><collection>Health Research Premium Collection</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Global</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kumar, Rahul</au><au>Janbandhu, Shaileshkumar Y.</au><au>Sukhadeve, Gaurav K.</au><au>Gedam, Rupesh S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Visible light assisted surface plasmon resonance triggered Ag/ZnO nanocomposites: synthesis and performance towards degradation of indigo carmine dye</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2023-09-01</date><risdate>2023</risdate><volume>30</volume><issue>44</issue><spage>98619</spage><epage>98631</epage><pages>98619-98631</pages><issn>1614-7499</issn><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>
Water pollution caused by organic compounds, generated from different industries, has gained attention worldwide today. In this regard, significant efforts have been made for a suitable dye degradation technology. Zinc oxide (ZnO)–based photocatalysts are considered novel materials to degrade organic effluents in contaminated water. The facile synthesis of Ag/ZnO nanocomposites and its application for the enhanced degradation of indigo carmine (IC) dye under visible light irradiation is reported in this paper. The prepared photocatalysts were characterized using various analytical techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron (XPS) spectroscopy, FTIR, Raman, impedance study, UV–Vis, and photoluminescence (PL). Prepared Ag/ZnO nanocomposites were tested for degradation of IC dye in visible light. The degradation efficiency of IC dye was found to be 95.71% in 120 min, with a rate constant of 0.02021 min
−1
. This improved photocatalytic activity of Ag/ZnO nanocomposites was mainly due to the absorption of visible light caused by surface plasmon resonance (SPR) derived from Ag nanoparticles (NPs) and electron–hole separation. Radical trapping experiments suggest that holes (h
+
) and superoxide radical (O
2
•
–
) are the key factors in photocatalytic IC dye degradation.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>36053425</pmid><doi>10.1007/s11356-022-22745-y</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Environmental science and pollution research international, 2023-09, Vol.30 (44), p.98619-98631 |
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| language | eng |
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| source | MEDLINE; SpringerNature Journals |
| subjects | Advanced Materials for Energy & Applications Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Carmine Catalysis Catalytic activity Degradation Dyes Earth and Environmental Science Ecotoxicology Electrons Environment Environmental Chemistry Environmental Health High resolution electron microscopy Indigo Indigo Carmine Irradiation Light Light irradiation Metal Nanoparticles - chemistry Microscopy Nanocomposites Nanocomposites - chemistry Nanoparticles Organic compounds Performance degradation Photocatalysis Photocatalysts Photodegradation Photoelectrons Photoluminescence Photons Resonance Scanning electron microscopy Silver Silver - chemistry Surface Plasmon Resonance Synthesis Transmission electron microscopy Waste Water Technology Water Management Water pollution Water Pollution Control X ray photoelectron spectroscopy X-ray diffraction Zinc oxide Zinc Oxide - chemistry Zinc oxides |
| title | Visible light assisted surface plasmon resonance triggered Ag/ZnO nanocomposites: synthesis and performance towards degradation of indigo carmine dye |
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