One and Two‐Photon Excited Fluorescence Optimization of Metal–Organic Frameworks with Symmetry‐Reduced AIEgen‐Ligand

By designing a tetraphenylethylene (TPE)‐based AIEgen‐ligand with reduced symmetry, we obtained two alkaline‐earth metal‐based MOFs (LIFM‐102 and LIFM‐103) with dense packing structures and low porosity as proved by single‐crystal X‐ray diffraction and CO2 sorption data. Excitingly, the desolvated M...

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Veröffentlicht in:	Angewandte Chemie International Edition 2022-10, Vol.61 (43), p.e202211356-n/a
Hauptverfasser:	Wang, Shi‐Cheng, Zhang, Qiang‐Sheng, Wang, Zheng, Zheng, Lin, Zhang, Xiao‐Dong, Fan, Ya‐Nan, Fu, Peng‐Yan, Xiong, Xiao‐Hong, Pan, Mei
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Conformation Crystal structure Dense Packing Arrangement Fluorescence Ligands Metal-organic frameworks Optimization Photoluminescence Photons Porosity Stimuli-Responsive Fluorescence Symmetry Symmetry Reduced Ligand Two-Photon Excited Fluorescence
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