Characterization of Nanostructure of Rusts Formed on Weathering Steel
Nano-scale structures of rusts formed on the weathering steel surface were investigated. It has been shown that the key structure is an Fe(O, OH)6 network, which is different from crystalline FeOOH. Atomic structures were analyzed quantitatively by a combination of X-ray absorption fine structure (X...
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Veröffentlicht in: | ISIJ International 2002/12/15, Vol.42(12), pp.1534-1540 |
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creator | Kimura, Masao Suzuki, Tamaki Shigesato, Genichi Kihira, Hiroshi Suzuki, Shigeru |
description | Nano-scale structures of rusts formed on the weathering steel surface were investigated. It has been shown that the key structure is an Fe(O, OH)6 network, which is different from crystalline FeOOH. Atomic structures were analyzed quantitatively by a combination of X-ray absorption fine structure (XAFS) analysis including in situ observation under wet conditions, X-ray diffraction (XRD), and transmission electron microscopy (TEM). It has been shown that the Fe(O, OH)6 network structure evolves in the process of corrosion and a small amount of alloying elements such as chromium modifies the evolution process and the final morphology of rust. |
doi_str_mv | 10.2355/isijinternational.42.1534 |
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It has been shown that the Fe(O, OH)6 network structure evolves in the process of corrosion and a small amount of alloying elements such as chromium modifies the evolution process and the final morphology of rust.</description><identifier>ISSN: 0915-1559</identifier><identifier>EISSN: 1347-5460</identifier><identifier>DOI: 10.2355/isijinternational.42.1534</identifier><language>eng</language><publisher>The Iron and Steel Institute of Japan</publisher><subject>atomic structure ; corrosion ; iron oxyhydroxide ; network structure ; rust ; weathering steel ; X-ray absorption fine structure</subject><ispartof>ISIJ International, 2002/12/15, Vol.42(12), pp.1534-1540</ispartof><rights>The Iron and Steel Institute of Japan</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c585t-bee12999de641fbafd16535667dcf18368b540b5bf566825ebef5217cd2456c03</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,1883,27924,27925</link.rule.ids></links><search><creatorcontrib>Kimura, Masao</creatorcontrib><creatorcontrib>Suzuki, Tamaki</creatorcontrib><creatorcontrib>Shigesato, Genichi</creatorcontrib><creatorcontrib>Kihira, Hiroshi</creatorcontrib><creatorcontrib>Suzuki, Shigeru</creatorcontrib><title>Characterization of Nanostructure of Rusts Formed on Weathering Steel</title><title>ISIJ International</title><addtitle>ISIJ Int.</addtitle><description>Nano-scale structures of rusts formed on the weathering steel surface were investigated. It has been shown that the key structure is an Fe(O, OH)6 network, which is different from crystalline FeOOH. Atomic structures were analyzed quantitatively by a combination of X-ray absorption fine structure (XAFS) analysis including in situ observation under wet conditions, X-ray diffraction (XRD), and transmission electron microscopy (TEM). It has been shown that the Fe(O, OH)6 network structure evolves in the process of corrosion and a small amount of alloying elements such as chromium modifies the evolution process and the final morphology of rust.</description><subject>atomic structure</subject><subject>corrosion</subject><subject>iron oxyhydroxide</subject><subject>network structure</subject><subject>rust</subject><subject>weathering steel</subject><subject>X-ray absorption fine structure</subject><issn>0915-1559</issn><issn>1347-5460</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNplkE1Lw0AQhhdRsNT-h3jxlrqfSfYopVWhKGjF47LZTNotaVJ3Nwf99W7a0ksvMzA8zwvzInRP8JQyIR6tt1vbBnCtDrZrdTPldEoE41doRBjPU8EzfI1GWBKREiHkLZp4b0uMKS84I2yE5rONdtrEDPt3CEm6OnnTbeeD603oHQyHj94Hnyw6t4Mqicw36LCJSrtOPgNAc4duat14mJz2GH0t5qvZS7p8f36dPS1TIwoR0hKAUCllBRkndanrimSCiSzLK1OTgmVFKTguRVnHW0EFlFALSnJTUS4yg9kYPRxz96776cEHtbPeQNPoFrreK5rjPL7PIyiPoHGd9w5qtXd2p92vIlgN3amL7hSnauguuquju_VBr-FsahesaeDSJLKQB5ue5hBzxk0sWEHL_gED94e6</recordid><startdate>20020101</startdate><enddate>20020101</enddate><creator>Kimura, Masao</creator><creator>Suzuki, Tamaki</creator><creator>Shigesato, Genichi</creator><creator>Kihira, Hiroshi</creator><creator>Suzuki, Shigeru</creator><general>The Iron and Steel Institute of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20020101</creationdate><title>Characterization of Nanostructure of Rusts Formed on Weathering Steel</title><author>Kimura, Masao ; Suzuki, Tamaki ; Shigesato, Genichi ; Kihira, Hiroshi ; Suzuki, Shigeru</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c585t-bee12999de641fbafd16535667dcf18368b540b5bf566825ebef5217cd2456c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>atomic structure</topic><topic>corrosion</topic><topic>iron oxyhydroxide</topic><topic>network structure</topic><topic>rust</topic><topic>weathering steel</topic><topic>X-ray absorption fine structure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kimura, Masao</creatorcontrib><creatorcontrib>Suzuki, Tamaki</creatorcontrib><creatorcontrib>Shigesato, Genichi</creatorcontrib><creatorcontrib>Kihira, Hiroshi</creatorcontrib><creatorcontrib>Suzuki, Shigeru</creatorcontrib><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>ISIJ International</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kimura, Masao</au><au>Suzuki, Tamaki</au><au>Shigesato, Genichi</au><au>Kihira, Hiroshi</au><au>Suzuki, Shigeru</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of Nanostructure of Rusts Formed on Weathering Steel</atitle><jtitle>ISIJ International</jtitle><addtitle>ISIJ Int.</addtitle><date>2002-01-01</date><risdate>2002</risdate><volume>42</volume><issue>12</issue><spage>1534</spage><epage>1540</epage><pages>1534-1540</pages><issn>0915-1559</issn><eissn>1347-5460</eissn><abstract>Nano-scale structures of rusts formed on the weathering steel surface were investigated. 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subjects | atomic structure corrosion iron oxyhydroxide network structure rust weathering steel X-ray absorption fine structure |
title | Characterization of Nanostructure of Rusts Formed on Weathering Steel |
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