Influence of kinetic parameters on the textural and chemical properties of silsesquioxane materials obtained by sol-gel process

The hydrolytic sol-gel polymerisation of a "rigid" molecular precursor 1,4-C6H4(Si(OMe)3)2 and a more "flexible" one 1,4-C6H4(CH2CH2Si(OMe)3)2 was studied under varied conditions. Two solvents, MeOH and THF, were employed. The influence of the catalyst was determined by using TBA...

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Veröffentlicht in:Journal of materials chemistry 1999, Vol.9 (5), p.1149-1154
Hauptverfasser: CERVEAU, G, CORRIU, R. J. P, FISCHMEISTER-LEPEYTRE, C
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Sprache:eng
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