In-flight oxidation of high-alloy steels during plasma spraying

In-flight oxidation of high-alloy steel powder particles sprayed by a water stabilized plasma gun was studied. The particles were collected in liquid nitrogen, which enabled rapid cooling and prevention from further oxidation. Shrouding by two different gases (nitrogen–hydrogen mixture and acetylene...

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Veröffentlicht in:Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 1999-11, Vol.272 (1), p.199-206
Hauptverfasser: Volenı́k, K, Hanousek, F, Chráska, P, Ilavský, J, Neufuss, K
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container_start_page 199
container_title Materials science & engineering. A, Structural materials : properties, microstructure and processing
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creator Volenı́k, K
Hanousek, F
Chráska, P
Ilavský, J
Neufuss, K
description In-flight oxidation of high-alloy steel powder particles sprayed by a water stabilized plasma gun was studied. The particles were collected in liquid nitrogen, which enabled rapid cooling and prevention from further oxidation. Shrouding by two different gases (nitrogen–hydrogen mixture and acetylene) was carried out. The influence of both gases on the oxidation reaction was assessed by determining the oxygen content in particles quenched in liquid nitrogen. Acetylene was found to be significantly more effective in decreasing the oxygen content. The main method to study the composition of the oxidation products was Mössbauer spectroscopy. The dominant oxide phase found in the oxidation products was non-stoichiometric chromium-rich FeCr 2O 4. A comparison with previous results shows that if the particles are deposited onto a solid substrate instead of being quenched in liquid nitrogen, this oxide is converted in non-stoichiometric iron-rich FeCr 2O 4 during the relatively slow cooling of the plasma sprayed deposit.
doi_str_mv 10.1016/S0921-5093(99)00478-5
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source ScienceDirect Journals (5 years ago - present)
subjects Applied sciences
Exact sciences and technology
High-alloy steels
In-flight oxidation
Metallic coatings
Metals. Metallurgy
Plasma spray
Production techniques
Shrouding
Surface treatment
title In-flight oxidation of high-alloy steels during plasma spraying
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