Toward solid-state switchable mirrors using a zirconium oxide proton conductor

The unique optical properties of magnesium rare-earth alloys are interesting for making new types of solid-state electrochromic devices, based on hydrogen transport. These devices can reversibly switch between a transparent and a reflective state, when a potential difference is applied. The all-soli...

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Veröffentlicht in:Solid state ionics 2001-12, Vol.145 (1), p.17-24
Hauptverfasser: Mercier, Virginie M.M, van der Sluis, Paul
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van der Sluis, Paul
description The unique optical properties of magnesium rare-earth alloys are interesting for making new types of solid-state electrochromic devices, based on hydrogen transport. These devices can reversibly switch between a transparent and a reflective state, when a potential difference is applied. The all-solid state devices presently studied involve a zirconium oxide proton conductor. This paper discusses the deposition and preliminary characterisation of the solid-state electrolyte. It also gives some information about the performance of a symmetrical GdMg device tested in a hydrogen gas atmosphere. This stack is composed of a GdMgH x /Pd bottom electrode, a ZrO 2·(H 2O) x ·[H 2] y proton conductor and a Pd/GdMgH y /Pd top-electrode.
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subjects Applied sciences
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Electrochromic device
Exact sciences and technology
Fundamental areas of phenomenology (including applications)
Light-sensitive materials
Metal hydride
Optical materials
Optics
Physics
Solid-state electrolyte
ZrO 2·(H 2O) x·[H 2] y
title Toward solid-state switchable mirrors using a zirconium oxide proton conductor
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