WO3 thin film prepared by pecvd technique and its gas sensing properties to NO2

Tungsten oxide films have been successfully fabricated from tungsten oxychloride (WOCl4) precursor by using plasma enhanced vapor deposition (PECVD) technique. The films were deposited onto silicon substrates and ceramic tubes maintained at 100°C under a constant operating pressure of He-O2 gas mixt...

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Veröffentlicht in:Journal of materials science 2001-01, Vol.36 (10), p.2535-2538
Hauptverfasser: Tong, Maosong, Dai, Guorui, Wu, Yuanda, He, Xiuli, Gao, Dingsan
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container_end_page 2538
container_issue 10
container_start_page 2535
container_title Journal of materials science
container_volume 36
creator Tong, Maosong
Dai, Guorui
Wu, Yuanda
He, Xiuli
Gao, Dingsan
description Tungsten oxide films have been successfully fabricated from tungsten oxychloride (WOCl4) precursor by using plasma enhanced vapor deposition (PECVD) technique. The films were deposited onto silicon substrates and ceramic tubes maintained at 100°C under a constant operating pressure of He-O2 gas mixtures. The compositions and the structures of the thin films have been investigated by means of anaysis methods, such as XRD, XPS, UV and IR. The as-deposited WO3 thin films were amorphous state and became crystalline after annealing above 400°C. The surface analysis of the films indicates that stoichiometry O/W is 2.77 : 1. The gas sensing measurements of the WO3 thin film sensors indicate that these sensors have a high sensitivity, excellent selectivity and quick response behavior to NO2.
doi_str_mv 10.1023/a:1017950619864
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subjects Analytical chemistry
Chemical analysis and related physical methods of analysis
Chemical vapor deposition
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Chemistry
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Gas mixtures
Gas sensors
General equipment and techniques
General, instrumentation
Instruments, apparatus, components and techniques common to several branches of physics and astronomy
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Nitrogen dioxide
Oxide coatings
Physics
Selectivity
Sensors (chemical, optical, electrical, movement, gas, etc.)
remote sensing
Silicon
Silicon substrates
Stoichiometry
Surface analysis (chemical)
Thin films
Tubes
Tungsten oxides
Vapor deposition
title WO3 thin film prepared by pecvd technique and its gas sensing properties to NO2
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