Seeded-growth self-assembled polymerization of a ferrocene-bearing palladium()-terpyridyl bimetallic complex

A new bimetallic complex containing a 4′-ferrocenyl-(2,2′:6′,2′′-terpyridine)palladium core with polyethylene glycol-based pyridine is applied in seeded-growth self-assembled supramolecular polymerization, which affords nanoribbons with controllable lengths and the process follows a first-order reac...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-09, Vol.58 (71), p.9878-9881
Hauptverfasser: Li, Zikang, Lau, Mei-Tung, Li, Jiahua, Qiu, Feng, Meng, Zhengong, Wong, Wai-Yeung
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container_end_page 9881
container_issue 71
container_start_page 9878
container_title Chemical communications (Cambridge, England)
container_volume 58
creator Li, Zikang
Lau, Mei-Tung
Li, Jiahua
Qiu, Feng
Meng, Zhengong
Wong, Wai-Yeung
description A new bimetallic complex containing a 4′-ferrocenyl-(2,2′:6′,2′′-terpyridine)palladium core with polyethylene glycol-based pyridine is applied in seeded-growth self-assembled supramolecular polymerization, which affords nanoribbons with controllable lengths and the process follows a first-order reaction kinetics. This approach is successfully demonstrated for a bimetallic organic complex for the first time. A bimetallic complex containing a 4′-ferrocenyl-(2,2′:6′,2′′-terpyridine)palladium core with polyethylene glycol-based pyridine is applied in seeded-growth supramolecular polymerization, which affords nanoribbons with controllable dimensions.
doi_str_mv 10.1039/d2cc02375j
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Bimetals
Nanoribbons
Palladium
Polyethylene glycol
Polymerization
Reaction kinetics
Self-assembly
title Seeded-growth self-assembled polymerization of a ferrocene-bearing palladium()-terpyridyl bimetallic complex
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