Lattice vibrations and bulk properties of ceramics-forming materials: Piezoeffect in SiC and elasticity of ZrO2

The role of lattice vibrations in the crystal properties related to the homogeneous strains is discussed. Such properties depend on the individual phonon characteristics measurable by vibrational spectroscopy. So, being applicable to powderlike samples, it can provide an indirect information on thos...

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Veröffentlicht in:Journal of materials science 1999-10, Vol.34 (19), p.4845-4851
Hauptverfasser: Mirgorodsky, Andrei P, Smirnov, Mikhail B, Merle-Mejean, Thérèse, Quintard, Pierre E
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container_issue 19
container_start_page 4845
container_title Journal of materials science
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creator Mirgorodsky, Andrei P
Smirnov, Mikhail B
Merle-Mejean, Thérèse
Quintard, Pierre E
description The role of lattice vibrations in the crystal properties related to the homogeneous strains is discussed. Such properties depend on the individual phonon characteristics measurable by vibrational spectroscopy. So, being applicable to powderlike samples, it can provide an indirect information on those bulk characteristics which cannot be directly measured for such samples. The piezoelectricity of cubic SiC, and the elasticity of tetragonal ZrO2 are considered along with the phonon spectra. Thus the mechanism of the polarization of sphalerite-like materials is elucidated; a contradiction between the elastic properties of the t-ZrO2 lattice and the conventional interpretation of its Raman spectra is revealed.
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subjects Crystal lattices
Elastic properties
Elasticity
Electrons
Lattice vibration
Materials science
Phonons
Piezoelectricity
Raman spectra
Silicon carbide
Spectrum analysis
Zincblende
Zirconium dioxide
title Lattice vibrations and bulk properties of ceramics-forming materials: Piezoeffect in SiC and elasticity of ZrO2
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