The electrochemical oxidation of tetrahydrofuran in sulphuric acid solution
The electrochemical behaviour of THF on Pt in H 2SO 4 using cyclic voltammetry was examined. The products were identified with GC–MS. The two basic products were found to be γ-butyrolactone and 2-hydroxy-tetrahydrofuran with current efficiencies up to 54.4 and 41.2% correspondingly. In addition, the...
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| Veröffentlicht in: | Electrochimica acta 1999-01, Vol.44 (19), p.3295-3301 |
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| container_title | Electrochimica acta |
| container_volume | 44 |
| creator | Avgousti, Christiana Georgolios, Nickos Kyriacou, George Ritzoulis, George |
| description | The electrochemical behaviour of THF on Pt in H
2SO
4 using cyclic voltammetry was examined. The products were identified with GC–MS. The two basic products were found to be γ-butyrolactone and 2-hydroxy-tetrahydrofuran with current efficiencies up to 54.4 and 41.2% correspondingly. In addition, the UPD of Tl and Cu were shown to inhibit THF oxidation, since the deposits probably block active sites on the electrode surface. |
| doi_str_mv | 10.1016/S0013-4686(99)00051-1 |
| format | Article |
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2SO
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| ispartof | Electrochimica acta, 1999-01, Vol.44 (19), p.3295-3301 |
| issn | 0013-4686 1873-3859 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Chemistry Electrochemical oxidation Electrochemistry Exact sciences and technology GC–MS General and physical chemistry Kinetics and mechanism of reactions Succinic acid Tetrahydrofuran Underpotential deposition γ-Butyrolactone |
| title | The electrochemical oxidation of tetrahydrofuran in sulphuric acid solution |
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