Lithium-induced moments in tetragonal YBCO

The magnetic susceptibility of various YBa 2Cu 3− x Li x O 6+ ϵ samples with 0< x

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Veröffentlicht in:Solid state communications 1999-02, Vol.109 (8), p.531-536
Hauptverfasser: Nicolas-Francillon, M., Maury, F., Nanot, M., Ollitrault-Fichet, R.
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container_end_page 536
container_issue 8
container_start_page 531
container_title Solid state communications
container_volume 109
creator Nicolas-Francillon, M.
Maury, F.
Nanot, M.
Ollitrault-Fichet, R.
description The magnetic susceptibility of various YBa 2Cu 3− x Li x O 6+ ϵ samples with 0< x
doi_str_mv 10.1016/S0038-1098(98)00555-9
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All the samples were tetragonal and single phase. Considering only the cell parameter variation does not allow us to conclude what site is occupied by lithium with certainty, the chain site being the most probable because a contraction of the c-axis is observed. As the lithium concentration increases, one observes the disappearance of the three-dimensional (3D) antiferromagnetism in favour of a paramagnetic system revealing the formation of disordered localised magnetic moments. The observed Curie-type behaviour shows that the substitution of one lithium for one copper ion induces an effective moment of (1.13±0.07) μ B/Li, independent of the lithium concentration as long as the oxygen content remains equal to (6.03±0.05). This effective moment is identical to the one induced by lithium in the orthorhombic YBCOLi x materials which leads to the conclusion that lithium occupies the same site in both systems. 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All the samples were tetragonal and single phase. Considering only the cell parameter variation does not allow us to conclude what site is occupied by lithium with certainty, the chain site being the most probable because a contraction of the c-axis is observed. As the lithium concentration increases, one observes the disappearance of the three-dimensional (3D) antiferromagnetism in favour of a paramagnetic system revealing the formation of disordered localised magnetic moments. The observed Curie-type behaviour shows that the substitution of one lithium for one copper ion induces an effective moment of (1.13±0.07) μ B/Li, independent of the lithium concentration as long as the oxygen content remains equal to (6.03±0.05). This effective moment is identical to the one induced by lithium in the orthorhombic YBCOLi x materials which leads to the conclusion that lithium occupies the same site in both systems. 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High- Tc-superconductors</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Exact sciences and technology</subject><subject>Magnetic properties and materials</subject><subject>Magnetically ordered materials: other intrinsic properties</subject><subject>Physics</subject><subject>Saturation moments and magnetic susceptibilities</subject><issn>0038-1098</issn><issn>1879-2766</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNqFkM1LxDAQxYMouK7-CUIPIipUp0mTJifRxS9Y2IN68BTSdKqRfqxJKvjf23UXPQoDc_m9efMeIYcZnGeQiYtHACbTDJQ8UfIUgHOeqi0yyWShUloIsU0mv8gu2QvhHQAKWWQTcjZ38c0Nbeq6arBYJW3fYhdD4rokYvTmte9Mk7xczxb7ZKc2TcCDzZ6S59ubp9l9Ol_cPcyu5qllooiplKVVTFDDWU3HDzgyTstS5VJQViIicCZyY6CkUihWstrWeS0oVFwwwymbkuP13aXvPwYMUbcuWGwa02E_BE2FKiQrYAT5GrS-D8FjrZfetcZ_6Qz0qhn904xexdbj_DSj1ag72hiYYE1Te9NZF_7EQuYK5IhdrjEcw3469DpYh91YkvNoo65694_RN-d1dZk</recordid><startdate>19990217</startdate><enddate>19990217</enddate><creator>Nicolas-Francillon, M.</creator><creator>Maury, F.</creator><creator>Nanot, M.</creator><creator>Ollitrault-Fichet, R.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>19990217</creationdate><title>Lithium-induced moments in tetragonal YBCO</title><author>Nicolas-Francillon, M. ; Maury, F. ; Nanot, M. ; Ollitrault-Fichet, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-88bc9362a53f28795e352bb948623beee05364aa0b28693b3fcf4f620d563a523</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>A. 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All the samples were tetragonal and single phase. Considering only the cell parameter variation does not allow us to conclude what site is occupied by lithium with certainty, the chain site being the most probable because a contraction of the c-axis is observed. As the lithium concentration increases, one observes the disappearance of the three-dimensional (3D) antiferromagnetism in favour of a paramagnetic system revealing the formation of disordered localised magnetic moments. The observed Curie-type behaviour shows that the substitution of one lithium for one copper ion induces an effective moment of (1.13±0.07) μ B/Li, independent of the lithium concentration as long as the oxygen content remains equal to (6.03±0.05). This effective moment is identical to the one induced by lithium in the orthorhombic YBCOLi x materials which leads to the conclusion that lithium occupies the same site in both systems. In pure YBCO 6+ ϵ , an excess of one oxygen ion in the chains is found to give rise to one Bohr magneton.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0038-1098(98)00555-9</doi><tpages>6</tpages></addata></record>
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subjects A. High- Tc-superconductors
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Exact sciences and technology
Magnetic properties and materials
Magnetically ordered materials: other intrinsic properties
Physics
Saturation moments and magnetic susceptibilities
title Lithium-induced moments in tetragonal YBCO
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