Lithium-induced moments in tetragonal YBCO
The magnetic susceptibility of various YBa 2Cu 3− x Li x O 6+ ϵ samples with 0< x
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Veröffentlicht in: | Solid state communications 1999-02, Vol.109 (8), p.531-536 |
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container_title | Solid state communications |
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creator | Nicolas-Francillon, M. Maury, F. Nanot, M. Ollitrault-Fichet, R. |
description | The magnetic susceptibility of various YBa
2Cu
3−
x
Li
x
O
6+
ϵ
samples with 0<
x |
doi_str_mv | 10.1016/S0038-1098(98)00555-9 |
format | Article |
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2Cu
3−
x
Li
x
O
6+
ϵ
samples with 0<
x<0.4 was measured in a field of 1
T in the 4.5–300
K temperature range. All the samples were tetragonal and single phase. Considering only the cell parameter variation does not allow us to conclude what site is occupied by lithium with certainty, the chain site being the most probable because a contraction of the
c-axis is observed. As the lithium concentration increases, one observes the disappearance of the three-dimensional (3D) antiferromagnetism in favour of a paramagnetic system revealing the formation of disordered localised magnetic moments. The observed Curie-type behaviour shows that the substitution of one lithium for one copper ion induces an effective moment of (1.13±0.07)
μ
B/Li, independent of the lithium concentration as long as the oxygen content remains equal to (6.03±0.05). This effective moment is identical to the one induced by lithium in the orthorhombic YBCOLi
x
materials which leads to the conclusion that lithium occupies the same site in both systems. In pure YBCO
6+
ϵ
, an excess of one oxygen ion in the chains is found to give rise to one Bohr magneton.</description><identifier>ISSN: 0038-1098</identifier><identifier>EISSN: 1879-2766</identifier><identifier>DOI: 10.1016/S0038-1098(98)00555-9</identifier><identifier>CODEN: SSCOA4</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>A. High- Tc-superconductors ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Exact sciences and technology ; Magnetic properties and materials ; Magnetically ordered materials: other intrinsic properties ; Physics ; Saturation moments and magnetic susceptibilities</subject><ispartof>Solid state communications, 1999-02, Vol.109 (8), p.531-536</ispartof><rights>1999 Elsevier Science Ltd</rights><rights>1999 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-88bc9362a53f28795e352bb948623beee05364aa0b28693b3fcf4f620d563a523</citedby><cites>FETCH-LOGICAL-c367t-88bc9362a53f28795e352bb948623beee05364aa0b28693b3fcf4f620d563a523</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0038109898005559$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1684908$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Nicolas-Francillon, M.</creatorcontrib><creatorcontrib>Maury, F.</creatorcontrib><creatorcontrib>Nanot, M.</creatorcontrib><creatorcontrib>Ollitrault-Fichet, R.</creatorcontrib><title>Lithium-induced moments in tetragonal YBCO</title><title>Solid state communications</title><description>The magnetic susceptibility of various YBa
2Cu
3−
x
Li
x
O
6+
ϵ
samples with 0<
x<0.4 was measured in a field of 1
T in the 4.5–300
K temperature range. All the samples were tetragonal and single phase. Considering only the cell parameter variation does not allow us to conclude what site is occupied by lithium with certainty, the chain site being the most probable because a contraction of the
c-axis is observed. As the lithium concentration increases, one observes the disappearance of the three-dimensional (3D) antiferromagnetism in favour of a paramagnetic system revealing the formation of disordered localised magnetic moments. The observed Curie-type behaviour shows that the substitution of one lithium for one copper ion induces an effective moment of (1.13±0.07)
μ
B/Li, independent of the lithium concentration as long as the oxygen content remains equal to (6.03±0.05). This effective moment is identical to the one induced by lithium in the orthorhombic YBCOLi
x
materials which leads to the conclusion that lithium occupies the same site in both systems. In pure YBCO
6+
ϵ
, an excess of one oxygen ion in the chains is found to give rise to one Bohr magneton.</description><subject>A. High- Tc-superconductors</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Exact sciences and technology</subject><subject>Magnetic properties and materials</subject><subject>Magnetically ordered materials: other intrinsic properties</subject><subject>Physics</subject><subject>Saturation moments and magnetic susceptibilities</subject><issn>0038-1098</issn><issn>1879-2766</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNqFkM1LxDAQxYMouK7-CUIPIipUp0mTJifRxS9Y2IN68BTSdKqRfqxJKvjf23UXPQoDc_m9efMeIYcZnGeQiYtHACbTDJQ8UfIUgHOeqi0yyWShUloIsU0mv8gu2QvhHQAKWWQTcjZ38c0Nbeq6arBYJW3fYhdD4rokYvTmte9Mk7xczxb7ZKc2TcCDzZ6S59ubp9l9Ol_cPcyu5qllooiplKVVTFDDWU3HDzgyTstS5VJQViIicCZyY6CkUihWstrWeS0oVFwwwymbkuP13aXvPwYMUbcuWGwa02E_BE2FKiQrYAT5GrS-D8FjrZfetcZ_6Qz0qhn904xexdbj_DSj1ag72hiYYE1Te9NZF_7EQuYK5IhdrjEcw3469DpYh91YkvNoo65694_RN-d1dZk</recordid><startdate>19990217</startdate><enddate>19990217</enddate><creator>Nicolas-Francillon, M.</creator><creator>Maury, F.</creator><creator>Nanot, M.</creator><creator>Ollitrault-Fichet, R.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>19990217</creationdate><title>Lithium-induced moments in tetragonal YBCO</title><author>Nicolas-Francillon, M. ; Maury, F. ; Nanot, M. ; Ollitrault-Fichet, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-88bc9362a53f28795e352bb948623beee05364aa0b28693b3fcf4f620d563a523</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>A. High- Tc-superconductors</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Exact sciences and technology</topic><topic>Magnetic properties and materials</topic><topic>Magnetically ordered materials: other intrinsic properties</topic><topic>Physics</topic><topic>Saturation moments and magnetic susceptibilities</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nicolas-Francillon, M.</creatorcontrib><creatorcontrib>Maury, F.</creatorcontrib><creatorcontrib>Nanot, M.</creatorcontrib><creatorcontrib>Ollitrault-Fichet, R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nicolas-Francillon, M.</au><au>Maury, F.</au><au>Nanot, M.</au><au>Ollitrault-Fichet, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lithium-induced moments in tetragonal YBCO</atitle><jtitle>Solid state communications</jtitle><date>1999-02-17</date><risdate>1999</risdate><volume>109</volume><issue>8</issue><spage>531</spage><epage>536</epage><pages>531-536</pages><issn>0038-1098</issn><eissn>1879-2766</eissn><coden>SSCOA4</coden><abstract>The magnetic susceptibility of various YBa
2Cu
3−
x
Li
x
O
6+
ϵ
samples with 0<
x<0.4 was measured in a field of 1
T in the 4.5–300
K temperature range. All the samples were tetragonal and single phase. Considering only the cell parameter variation does not allow us to conclude what site is occupied by lithium with certainty, the chain site being the most probable because a contraction of the
c-axis is observed. As the lithium concentration increases, one observes the disappearance of the three-dimensional (3D) antiferromagnetism in favour of a paramagnetic system revealing the formation of disordered localised magnetic moments. The observed Curie-type behaviour shows that the substitution of one lithium for one copper ion induces an effective moment of (1.13±0.07)
μ
B/Li, independent of the lithium concentration as long as the oxygen content remains equal to (6.03±0.05). This effective moment is identical to the one induced by lithium in the orthorhombic YBCOLi
x
materials which leads to the conclusion that lithium occupies the same site in both systems. In pure YBCO
6+
ϵ
, an excess of one oxygen ion in the chains is found to give rise to one Bohr magneton.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0038-1098(98)00555-9</doi><tpages>6</tpages></addata></record> |
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issn | 0038-1098 1879-2766 |
language | eng |
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source | Elsevier ScienceDirect Journals |
subjects | A. High- Tc-superconductors Condensed matter: electronic structure, electrical, magnetic, and optical properties Exact sciences and technology Magnetic properties and materials Magnetically ordered materials: other intrinsic properties Physics Saturation moments and magnetic susceptibilities |
title | Lithium-induced moments in tetragonal YBCO |
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