α-SiC layers grown on silicon via nano-sized silicon nitride precursor route

alpha -SiC thin layers were successfully grown on silicon (111) by pyrolysis of the organic liquid dip-coating films and polyimide Langmuir-Blodgett (LB) films containing nanometer sized amorphous silicon nitride powders (NASNP) at 900-1000 degree C in vacuum. The products were characterized by X-ra...

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Veröffentlicht in:Thin solid films 1999-05, Vol.345 (2), p.188-191
Hauptverfasser: Liu, Ruchuan, Yang, Beifang, Fu, Zhengping, Chen, Qian, Hong, Lin, Li, Ming, Liu, Zongcai, Ruan, Yaozhong
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container_end_page 191
container_issue 2
container_start_page 188
container_title Thin solid films
container_volume 345
creator Liu, Ruchuan
Yang, Beifang
Fu, Zhengping
Chen, Qian
Hong, Lin
Li, Ming
Liu, Zongcai
Ruan, Yaozhong
description alpha -SiC thin layers were successfully grown on silicon (111) by pyrolysis of the organic liquid dip-coating films and polyimide Langmuir-Blodgett (LB) films containing nanometer sized amorphous silicon nitride powders (NASNP) at 900-1000 degree C in vacuum. The products were characterized by X-ray diffraction (XRD), infrared absorption (IR) and Raman spectra, the results of which strongly support the formation of preferred orientated 4H-SiC in the layers by pyrolysis of LB films containing NASNP. Based on the IR spectra of samples pyrolyzed at different temperatures and the computed values of the Gibbs free energy changes of the reactions, the mechanism of formation of alpha -SiC is discussed.
doi_str_mv 10.1016/S0040-6090(99)00047-4
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The products were characterized by X-ray diffraction (XRD), infrared absorption (IR) and Raman spectra, the results of which strongly support the formation of preferred orientated 4H-SiC in the layers by pyrolysis of LB films containing NASNP. 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subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Liquid phase epitaxy
deposition from liquid phases (melts, solutions, and surface layers on liquids)
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Nanoscale materials and structures: fabrication and characterization
Physics
title α-SiC layers grown on silicon via nano-sized silicon nitride precursor route
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