Two-in-One Approach toward White-Light Emissions of Dimeric B/N Lewis Pairs by Tuning the Ortho-Substitution Effect

Two-in-One Approach toward White-Light Emissions of Dimeric B/N Lewis Pairs by Tuning the Ortho-Substitution Effect

A new family of dimeric B/N Lewis pairs with sterically tunable substitutions has been accomplished using the Two-in-One design strategy. Their structures are characteristic of doubly B/N-containing cores, and the electronic interactions between B and N centers can be modulated by the steric effects...

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Veröffentlicht in:Organic letters 2022-07, Vol.24 (29), p.5497-5502
Hauptverfasser: Shi, Yafei, Li, Chenglong, Ma, Hongwei, Cao, Zhao, Liu, Kanglei, Yin, Xiaodong, Wang, Nan, Chen, Pangkuan
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container_end_page 5502
container_issue 29
container_start_page 5497
container_title Organic letters
container_volume 24
creator Shi, Yafei
Li, Chenglong
Ma, Hongwei
Cao, Zhao
Liu, Kanglei
Yin, Xiaodong
Wang, Nan
Chen, Pangkuan
description A new family of dimeric B/N Lewis pairs with sterically tunable substitutions has been accomplished using the Two-in-One design strategy. Their structures are characteristic of doubly B/N-containing cores, and the electronic interactions between B and N centers can be modulated by the steric effects of ortho-substitutions from methyl groups. Interestingly, unique white-light emissions were achieved for 2M′2BNM and 1M2BNM, ascribed to the integration of two triarylborane species (Bsp 2- and Bsp 3-hybridization) into one single molecule.
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title Two-in-One Approach toward White-Light Emissions of Dimeric B/N Lewis Pairs by Tuning the Ortho-Substitution Effect
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