The deposition of oriented diamond film by hot-filament chemical vapor deposition with separate reactant gas

A (110)-oriented diamond film was deposited by hot filament chemical vapor deposition with H2 and CH4 separately introduced into the reactive zone. The film with a degree of orientation I(220)/I(111) of more than 200% and deposition rate of 2–3 μm/h was obtained for a deposition time of 17 h. The lo...

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Veröffentlicht in:Journal of materials research 1999-08, Vol.14 (8), p.3196-3199
Hauptverfasser: Chen, G. C., Sun, C., Huang, R. F., Wen, L. S., Jiang, D. Y., Yao, X. Z.
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container_end_page 3199
container_issue 8
container_start_page 3196
container_title Journal of materials research
container_volume 14
creator Chen, G. C.
Sun, C.
Huang, R. F.
Wen, L. S.
Jiang, D. Y.
Yao, X. Z.
description A (110)-oriented diamond film was deposited by hot filament chemical vapor deposition with H2 and CH4 separately introduced into the reactive zone. The film with a degree of orientation I(220)/I(111) of more than 200% and deposition rate of 2–3 μm/h was obtained for a deposition time of 17 h. The long deposition time enlarged the grain size and enhanced the degree of orientation, but too long a deposition time resulted in random growth. The temperature field was measured and also calculated using a simple model. Both results showed that a temperature field existed with varied gradients along the normal of substrate surface. The (110)-oriented diamond film was deposited in the zone with negative temperature gradient. The change in orientation occurring for long deposition times was ascribed to the change of temperature gradient.
doi_str_mv 10.1557/JMR.1999.0430
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title The deposition of oriented diamond film by hot-filament chemical vapor deposition with separate reactant gas
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