Photocatalytic Cleavage of C(sp3)−N Bond in Trialkylamines to Dialkylamines and Olefins
Development of a new and green strategy for C(sp3)−N bond cleavage is very interesting. Herein, photocatalytic cleavage of the C(sp3)−N bond of trialkylamines was achieved, with concurrent formation of dialkylamines and olefins. It was found that a rationally designed 2D‐Bi2WO6@1D‐LaPO4 heterostruct...
Gespeichert in:
| Veröffentlicht in: | ChemSusChem 2022-09, Vol.15 (18), p.e202201119-n/a |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 18 |
| container_start_page | e202201119 |
| container_title | ChemSusChem |
| container_volume | 15 |
| creator | Zhai, Jianxin Zhou, Baowen Wu, Haihong Jia, Shuaiqiang Chu, Mengen Han, Shitao Xia, Wei He, Mingyuan Han, Buxing |
| description | Development of a new and green strategy for C(sp3)−N bond cleavage is very interesting. Herein, photocatalytic cleavage of the C(sp3)−N bond of trialkylamines was achieved, with concurrent formation of dialkylamines and olefins. It was found that a rationally designed 2D‐Bi2WO6@1D‐LaPO4 heterostructure was very efficient for the reaction due to its high light collection efficiency and unique catalytic properties. The strategy could be used for different trialkylamines, including triethylamine, tri‐n‐propylamine, and ethyl‐di‐isopropylamine. The mechanistic investigation indicated that the catalyst with heterostructure was not only favorable for charge carrier separation but also rendered excited electrons with high reduction capacity. This work opens a way for C(sp3)−N bond cleavage of trialkylamines.
C−N cleavage: A rationally designed heterojunction of 2D‐Bi2WO6@1D‐LaPO4 is innovatively assembled for photocatalytic C(sp3)−N bond cleavage under ambient conditions, presenting a new and green strategy for dialkylamine synthesis from trialkylamines, with concurrent formation of the corresponding olefins. |
| doi_str_mv | 10.1002/cssc.202201119 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2688568992</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2715895065</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3509-b92b151d9add3dace2e37b7bf59d6034f93b601a30f88441862ef1f05ba56e143</originalsourceid><addsrcrecordid>eNqFkE1LAzEQhoMoWKtXzwEv9bA1H5t0c9T1E4oVWkFPIZtNNDXd1M1W6T_w7E_0l7iloujF0wzD8w4zDwD7GPUxQuRIx6j7BBGCMMZiA3RwxtOE8fRu87uneBvsxDhFiCPBeQfc3zyGJmjVKL9snIa5N-pFPRgYLMx7cU4PP97er-FJqEroKjipnfJPS69mrjIRNgGe_hqoFht5Y10Vd8GWVT6ava_aBbfnZ5P8MhmOLq7y42GiKUMiKQQpMMOlUGVJS6UNMXRQDArLRMkRTa2gBUdYUWSzLE3bP4ix2CJWKMYNTmkX9NZ753V4XpjYyJmL2nivKhMWURKeZYxnQpAWPfiDTsOirtrrJBlglgmGOGup_prSdYixNlbOazdT9VJiJFem5cq0_DbdBsQ68Oq8Wf5Dy3w8zn-ynyPngmk</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2715895065</pqid></control><display><type>article</type><title>Photocatalytic Cleavage of C(sp3)−N Bond in Trialkylamines to Dialkylamines and Olefins</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Zhai, Jianxin ; Zhou, Baowen ; Wu, Haihong ; Jia, Shuaiqiang ; Chu, Mengen ; Han, Shitao ; Xia, Wei ; He, Mingyuan ; Han, Buxing</creator><creatorcontrib>Zhai, Jianxin ; Zhou, Baowen ; Wu, Haihong ; Jia, Shuaiqiang ; Chu, Mengen ; Han, Shitao ; Xia, Wei ; He, Mingyuan ; Han, Buxing</creatorcontrib><description>Development of a new and green strategy for C(sp3)−N bond cleavage is very interesting. Herein, photocatalytic cleavage of the C(sp3)−N bond of trialkylamines was achieved, with concurrent formation of dialkylamines and olefins. It was found that a rationally designed 2D‐Bi2WO6@1D‐LaPO4 heterostructure was very efficient for the reaction due to its high light collection efficiency and unique catalytic properties. The strategy could be used for different trialkylamines, including triethylamine, tri‐n‐propylamine, and ethyl‐di‐isopropylamine. The mechanistic investigation indicated that the catalyst with heterostructure was not only favorable for charge carrier separation but also rendered excited electrons with high reduction capacity. This work opens a way for C(sp3)−N bond cleavage of trialkylamines.
C−N cleavage: A rationally designed heterojunction of 2D‐Bi2WO6@1D‐LaPO4 is innovatively assembled for photocatalytic C(sp3)−N bond cleavage under ambient conditions, presenting a new and green strategy for dialkylamine synthesis from trialkylamines, with concurrent formation of the corresponding olefins.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.202201119</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Alkenes ; Cleavage ; Current carriers ; green chemistry ; heterostructure ; Heterostructures ; nanostructures ; photocatalysis ; trialkylamines ; Triethylamine</subject><ispartof>ChemSusChem, 2022-09, Vol.15 (18), p.e202201119-n/a</ispartof><rights>2022 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3509-b92b151d9add3dace2e37b7bf59d6034f93b601a30f88441862ef1f05ba56e143</citedby><cites>FETCH-LOGICAL-c3509-b92b151d9add3dace2e37b7bf59d6034f93b601a30f88441862ef1f05ba56e143</cites><orcidid>0000-0003-0440-809X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.202201119$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.202201119$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Zhai, Jianxin</creatorcontrib><creatorcontrib>Zhou, Baowen</creatorcontrib><creatorcontrib>Wu, Haihong</creatorcontrib><creatorcontrib>Jia, Shuaiqiang</creatorcontrib><creatorcontrib>Chu, Mengen</creatorcontrib><creatorcontrib>Han, Shitao</creatorcontrib><creatorcontrib>Xia, Wei</creatorcontrib><creatorcontrib>He, Mingyuan</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><title>Photocatalytic Cleavage of C(sp3)−N Bond in Trialkylamines to Dialkylamines and Olefins</title><title>ChemSusChem</title><description>Development of a new and green strategy for C(sp3)−N bond cleavage is very interesting. Herein, photocatalytic cleavage of the C(sp3)−N bond of trialkylamines was achieved, with concurrent formation of dialkylamines and olefins. It was found that a rationally designed 2D‐Bi2WO6@1D‐LaPO4 heterostructure was very efficient for the reaction due to its high light collection efficiency and unique catalytic properties. The strategy could be used for different trialkylamines, including triethylamine, tri‐n‐propylamine, and ethyl‐di‐isopropylamine. The mechanistic investigation indicated that the catalyst with heterostructure was not only favorable for charge carrier separation but also rendered excited electrons with high reduction capacity. This work opens a way for C(sp3)−N bond cleavage of trialkylamines.
C−N cleavage: A rationally designed heterojunction of 2D‐Bi2WO6@1D‐LaPO4 is innovatively assembled for photocatalytic C(sp3)−N bond cleavage under ambient conditions, presenting a new and green strategy for dialkylamine synthesis from trialkylamines, with concurrent formation of the corresponding olefins.</description><subject>Alkenes</subject><subject>Cleavage</subject><subject>Current carriers</subject><subject>green chemistry</subject><subject>heterostructure</subject><subject>Heterostructures</subject><subject>nanostructures</subject><subject>photocatalysis</subject><subject>trialkylamines</subject><subject>Triethylamine</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKtXzwEv9bA1H5t0c9T1E4oVWkFPIZtNNDXd1M1W6T_w7E_0l7iloujF0wzD8w4zDwD7GPUxQuRIx6j7BBGCMMZiA3RwxtOE8fRu87uneBvsxDhFiCPBeQfc3zyGJmjVKL9snIa5N-pFPRgYLMx7cU4PP97er-FJqEroKjipnfJPS69mrjIRNgGe_hqoFht5Y10Vd8GWVT6ava_aBbfnZ5P8MhmOLq7y42GiKUMiKQQpMMOlUGVJS6UNMXRQDArLRMkRTa2gBUdYUWSzLE3bP4ix2CJWKMYNTmkX9NZ753V4XpjYyJmL2nivKhMWURKeZYxnQpAWPfiDTsOirtrrJBlglgmGOGup_prSdYixNlbOazdT9VJiJFem5cq0_DbdBsQ68Oq8Wf5Dy3w8zn-ynyPngmk</recordid><startdate>20220920</startdate><enddate>20220920</enddate><creator>Zhai, Jianxin</creator><creator>Zhou, Baowen</creator><creator>Wu, Haihong</creator><creator>Jia, Shuaiqiang</creator><creator>Chu, Mengen</creator><creator>Han, Shitao</creator><creator>Xia, Wei</creator><creator>He, Mingyuan</creator><creator>Han, Buxing</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0440-809X</orcidid></search><sort><creationdate>20220920</creationdate><title>Photocatalytic Cleavage of C(sp3)−N Bond in Trialkylamines to Dialkylamines and Olefins</title><author>Zhai, Jianxin ; Zhou, Baowen ; Wu, Haihong ; Jia, Shuaiqiang ; Chu, Mengen ; Han, Shitao ; Xia, Wei ; He, Mingyuan ; Han, Buxing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3509-b92b151d9add3dace2e37b7bf59d6034f93b601a30f88441862ef1f05ba56e143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alkenes</topic><topic>Cleavage</topic><topic>Current carriers</topic><topic>green chemistry</topic><topic>heterostructure</topic><topic>Heterostructures</topic><topic>nanostructures</topic><topic>photocatalysis</topic><topic>trialkylamines</topic><topic>Triethylamine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhai, Jianxin</creatorcontrib><creatorcontrib>Zhou, Baowen</creatorcontrib><creatorcontrib>Wu, Haihong</creatorcontrib><creatorcontrib>Jia, Shuaiqiang</creatorcontrib><creatorcontrib>Chu, Mengen</creatorcontrib><creatorcontrib>Han, Shitao</creatorcontrib><creatorcontrib>Xia, Wei</creatorcontrib><creatorcontrib>He, Mingyuan</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhai, Jianxin</au><au>Zhou, Baowen</au><au>Wu, Haihong</au><au>Jia, Shuaiqiang</au><au>Chu, Mengen</au><au>Han, Shitao</au><au>Xia, Wei</au><au>He, Mingyuan</au><au>Han, Buxing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photocatalytic Cleavage of C(sp3)−N Bond in Trialkylamines to Dialkylamines and Olefins</atitle><jtitle>ChemSusChem</jtitle><date>2022-09-20</date><risdate>2022</risdate><volume>15</volume><issue>18</issue><spage>e202201119</spage><epage>n/a</epage><pages>e202201119-n/a</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>Development of a new and green strategy for C(sp3)−N bond cleavage is very interesting. Herein, photocatalytic cleavage of the C(sp3)−N bond of trialkylamines was achieved, with concurrent formation of dialkylamines and olefins. It was found that a rationally designed 2D‐Bi2WO6@1D‐LaPO4 heterostructure was very efficient for the reaction due to its high light collection efficiency and unique catalytic properties. The strategy could be used for different trialkylamines, including triethylamine, tri‐n‐propylamine, and ethyl‐di‐isopropylamine. The mechanistic investigation indicated that the catalyst with heterostructure was not only favorable for charge carrier separation but also rendered excited electrons with high reduction capacity. This work opens a way for C(sp3)−N bond cleavage of trialkylamines.
C−N cleavage: A rationally designed heterojunction of 2D‐Bi2WO6@1D‐LaPO4 is innovatively assembled for photocatalytic C(sp3)−N bond cleavage under ambient conditions, presenting a new and green strategy for dialkylamine synthesis from trialkylamines, with concurrent formation of the corresponding olefins.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/cssc.202201119</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-0440-809X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1864-5631 |
| ispartof | ChemSusChem, 2022-09, Vol.15 (18), p.e202201119-n/a |
| issn | 1864-5631 1864-564X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2688568992 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Alkenes Cleavage Current carriers green chemistry heterostructure Heterostructures nanostructures photocatalysis trialkylamines Triethylamine |
| title | Photocatalytic Cleavage of C(sp3)−N Bond in Trialkylamines to Dialkylamines and Olefins |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T05%3A11%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photocatalytic%20Cleavage%20of%20C(sp3)%E2%88%92N%20Bond%20in%20Trialkylamines%20to%20Dialkylamines%20and%20Olefins&rft.jtitle=ChemSusChem&rft.au=Zhai,%20Jianxin&rft.date=2022-09-20&rft.volume=15&rft.issue=18&rft.spage=e202201119&rft.epage=n/a&rft.pages=e202201119-n/a&rft.issn=1864-5631&rft.eissn=1864-564X&rft_id=info:doi/10.1002/cssc.202201119&rft_dat=%3Cproquest_cross%3E2715895065%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2715895065&rft_id=info:pmid/&rfr_iscdi=true |