Stabilization of Imines and Hemiaminals in Water by an Endo‐Functionalized Container Molecule

Stabilizing water‐sensitive reaction intermediates is challenging but desirable for guiding reactions to desired products in water. Herein, we report that labile imine and hemiaminal functional groups can be stabilized inside a synthetic container compound, a water‐soluble naphthotube. The naphthotu...

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Veröffentlicht in:	Angewandte Chemie International Edition 2022-08, Vol.61 (35), p.e202208508-n/a
Hauptverfasser:	Li, Ming‐Shuang, Dong, Yi‐Wei, Quan, Mao, Jiang, Wei
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Aqueous solutions Containers Dehydration Functional groups Hemiaminals Hydrogen bonding Hydrophobicity Imines Intermediates Magnetic resonance spectroscopy Mass spectrometry Mass spectroscopy Microenvironments Naphthotube NMR NMR spectroscopy Nuclear magnetic resonance Reaction intermediates Room temperature Water-Sensitive Intermediates
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