Porphyrin derivative-based tandem response nanochannels triggered by Zn2+ and NO
We describe tandem response solid nanochannels tailored with a porphyrin derivative that show Zn2+ and NO gating behaviors with good selectivity, stability, and reversibility. EXAFS and fluorescence experiments showed that zinc coordinated with the porphyrin derivative as the ratio of 1 : 1 with the...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-07, Vol.58 (59), p.8286-8289 |
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creator | Xiao-Cui, Liang Shi-Qi, Cheng He, Qiang Zhong-Qiang, Zhou Zhao, Yanxi Sun, Yue |
description | We describe tandem response solid nanochannels tailored with a porphyrin derivative that show Zn2+ and NO gating behaviors with good selectivity, stability, and reversibility. EXAFS and fluorescence experiments showed that zinc coordinated with the porphyrin derivative as the ratio of 1 : 1 with the binding constant for 3.39 × 105 M−1. These studies are beneficial for simulating the physiological functions of ion/gas in organisms and have the potential for designing complicated logic circuits and fabricating novel biosensors. |
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EXAFS and fluorescence experiments showed that zinc coordinated with the porphyrin derivative as the ratio of 1 : 1 with the binding constant for 3.39 × 105 M−1. 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EXAFS and fluorescence experiments showed that zinc coordinated with the porphyrin derivative as the ratio of 1 : 1 with the binding constant for 3.39 × 105 M−1. 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EXAFS and fluorescence experiments showed that zinc coordinated with the porphyrin derivative as the ratio of 1 : 1 with the binding constant for 3.39 × 105 M−1. These studies are beneficial for simulating the physiological functions of ion/gas in organisms and have the potential for designing complicated logic circuits and fabricating novel biosensors.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2cc02163c</doi><tpages>4</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Biosensors Circuit design Logic circuits Nanochannels Porphyrins Selectivity |
title | Porphyrin derivative-based tandem response nanochannels triggered by Zn2+ and NO |
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