Porphyrin derivative-based tandem response nanochannels triggered by Zn2+ and NO

We describe tandem response solid nanochannels tailored with a porphyrin derivative that show Zn2+ and NO gating behaviors with good selectivity, stability, and reversibility. EXAFS and fluorescence experiments showed that zinc coordinated with the porphyrin derivative as the ratio of 1 : 1 with the...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-07, Vol.58 (59), p.8286-8289
Hauptverfasser: Xiao-Cui, Liang, Shi-Qi, Cheng, He, Qiang, Zhong-Qiang, Zhou, Zhao, Yanxi, Sun, Yue
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container_title Chemical communications (Cambridge, England)
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creator Xiao-Cui, Liang
Shi-Qi, Cheng
He, Qiang
Zhong-Qiang, Zhou
Zhao, Yanxi
Sun, Yue
description We describe tandem response solid nanochannels tailored with a porphyrin derivative that show Zn2+ and NO gating behaviors with good selectivity, stability, and reversibility. EXAFS and fluorescence experiments showed that zinc coordinated with the porphyrin derivative as the ratio of 1 : 1 with the binding constant for 3.39 × 105 M−1. These studies are beneficial for simulating the physiological functions of ion/gas in organisms and have the potential for designing complicated logic circuits and fabricating novel biosensors.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Biosensors
Circuit design
Logic circuits
Nanochannels
Porphyrins
Selectivity
title Porphyrin derivative-based tandem response nanochannels triggered by Zn2+ and NO
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